The mechanism of temperature-programmed desorption (TPD) of nitric acid chemisorbed on BaNa-Y was studied over the temperature range from 200 to 400 degrees C, in the presence and absence of CO. Nitric acid dissociates to form H(+) and NO(3)(-) when chemisorbed on BaNa-Y. The results of these experiments are consistent with H(+) and NO(3)(-) either reacting directly to produce OH and NO(2) or r...

A novel confined-space synthesis method has been developed to synthesize zeolite nanocrystals. Colloidal silica nanoparticles serving as the silica source as well as the hard template were embedded in the mesoporous carbon via in situ polymerization of furfuryl alcohol (FA) in the presence of tri-block copolymer (Pluronic P123), and then reacted with an alkaline aqueous solution (Na2O-Al2O3-H2O...

This study examines the performance of a new adsorbent, hexagonal nanostructured zeolite particles (HNZP) for acetone adsorption and compares the results with that of commercial mobil synthetic zeolite-5 (ZSM-5) type zeolite. The HNZP is a pure siliceous adsorbent with different values of pore diameter and surface area being adjustable by the manufacturing condition. The results indicate that a...

Werndrup, Pia. 2005. Synthesis, Structure Determination, and Sol-Gel Processing of Heterometallic Heteroleptic Alkoxide Complexes of Late Transition Metals. Doctor’s dissertation. ISSN 1652-6880, ISBN 91-576-7026-9. The thesis describes synthesis of single-source precursors (SSP) for sol-gel preparation of thin films and nanocomposites. The structures of the SSPs were determined by singlecrysta...

In this work, we have modified a synthesized Y-type zeolite (Si/Al = 2.5), with three different amines to investigate of the influence of adsorbent’s surface modification on CO2 selectivity over CH4. The pristine and amine-functionalized NaY zeolites were characterized by X-ray diffraction (XRD), thermal gravimetric analysis (TGA), Fourier transform infrared (FT-IR), and N2 adsorption. The resu...

Growth, nutrient balance, plasma ammonia levels and urinary p-cresol excretion were evaluated in growing pigs fed diets containing various levels of zeolite A or clinoptilolite. In one growth trial, crossbred pigs averaging 25 kg initial body weight were assigned to diets containing no zeolite, .3% zeolite A or .5% clinoptilolite for a 6-wk growing phase trial. Average daily gain (ADG), average...

A simple and versatile approach has been developed to synthesize different carbon/zeolite T functional membrane materials. The precursors of the membrane are composed of polyimide matrix and dispersed zeolite T particles. Membranes prepared by pyrolysis at 973 K showed excellent gas (H2, CO2, O2, N2, CH4) permeability and selectivity and the gas selectivity (O2/N2, CO2/CH4) of the functional me...