Yttria stabilized zirconia (YSZ) has been widely used as electrolyte in solid oxide fuel cell (SOFC). The effect of fabrication process on the properties of YSZ electrolyte thick film is discussed in the paper. With YSZ nano-powders of about 20-60nm as raw material, YSZ green adobe was fabricated by tape calendering process. Three-step sintering process was performed firstly holding at 1000°C f...

During the last three decades, a large number of investigations has been reported pertaining to the science and technology of solid oxide fuel cells (SOFCs) based mainly on the yttria-stabilized zirconia (YSZ) electrolyte. Because of the problems associated with the high temperature of operation ( ,-~ 1 000 ~ of the YSZ-based cells, there has been a substantial effort to develop alternative ele...

The colloidal behavior of nickel aqueous suspensions is studied and compared to that of NiO suspensions. Under acidic conditions, nickel readily dissolves, but no dissolution takes place at basic pH. Zeta potential is studied as a function of pH, showing that the isoelectric point (IEP) occurs at pH 3.5-4. Above the IEP there is a zeta potential plateau, which is associated to the predominance ...

Novel strategies based on spray-pyrolysis deposition are proposed to increase the triple-phase boundary (TPB) of La0.8Sr0.2MnO3-δ (LSM) cathodes in contact with yttria-stabilized zirconia (YSZ) electrolyte: (i) nanocrystalline LSM films deposited on as-prepared YSZ surface; (ii) the addition of poly(methyl methacrylate) microspheres as pore formers to further increase the porosity of the film c...

A NiO-MgO layered, binary thin oxide film has been prepared on a Mo(100) surface and characterized byAuger electron spectroscopy (AES), low energy electron diffraction (LEED) and high-resolution electron energy loss spectroscopy (HREELS or EELS). NiO grows epitaxially on a 20-monolayer (ML) MgO(100) film supported on the Mo(100) surface. At a NiO coverage of <1.8 monolayer, a new surface or int...

polyimide/nickel oxide (polyimide/nio) nanocomposite was successfully synthesized by sol gel technique, using pyromellitic dianhydriede (pmda), 4,4-oxydianiline (oda) and n,n-dimethylacetamide (dmac) and 10 wt% nickel titanate nanopowders (nps). fourier transform infrared spectrometry (ftir), x-ray diffraction (xrd), scanning electron microscopy (sem), and vibrating sample magnetometer (vsm) we...

the present research aims to synthesize the ha/ysz composite and to formulate ha/ysz-gic for improving the fluoride release of the set cement. experiments were performed by mixture design (md) method, and data analysis was carried out by mini- tab 14 software. the results showed that the combination of 25.891wt.% ha, 70.246wt.% zro2 and 3.86wt.% y2o3 has desirable fluoride release profile. comb...

Nanoporous nickel oxide (NiO x ) has been deposited with two different procedures of sintering (CS and RDS). Both samples display solid state oxidation at about 3.1 V vs Li+/Li. Upon sensitization of CS/RDS NiO x with erythrosine b (ERY), nickel oxide oxidation occurs at the same potential. Impedance spectroscopy revealed a higher charge transfer resistance for ERY-sensitized RDS NiO x with res...