Porous carbon materials with high specific surface areas and superhydrophobicity have attracted much research interest due to their potential application in the areas of water filtration, water/oil separation, and oil-spill cleanup. Most reported superhydrophobic porous carbon materials are fabricated by complex processes involving the use of catalysts and high temperatures but with low through...

The authors introduce a new parameterization for the dissipative particle dynamics simulations of lipid bilayers. In this parameterization, the conservative pairwise forces between beads of the same type in two different hydrophobic chains are chosen to be less repulsive than the water-water interaction, but the intrachain bead interactions are the same as the water-water interaction. For a cer...

We present a novel microfluidic approach for the generation of monodisperse oil droplets in water with ultra-low interfacial tensions. Using an oil-water-surfactant formulation under conditions close to the microemulsion phase transition, we actively controlled the surface tension at the liquid-liquid interface within the microfluidic device in order to produce monodisperse droplets. These drop...

The measured dynamic surface tension of a water drop in air saturated by heptane vapor shows a sharp decrease from about 60 mN m−1 to 40 mN m−1, and less after a certain adsorption time. The observed adsorption kinetics is analyzed by a theoretical model based on multilayer adsorption of alkanes from the vapor phase at the water surface. The model assumes a dependence of the kinetic coefficient...

Nanoparticles (NPs) and surfactants can spontaneously concentrate at the interface between two immiscible liquids, such as oil and water. Systems of high oil–water interfacial area, such as emulsions, are the basis of many industries and consumer products. Although NPs and surfactants are currently incorporated into many of these applications, their mutual interfacial behavior is not completely...

This work describes a droplet microarray for monitoring of enzymatic activity on a glass surface. These array are composed of features defined and separated by differential surface tension (surface tension array). A photolithographic method was used to create a series of circular hydrophilic spots delimited by a perfluorosilanated surface. The perfluorinated region had water contact angle on th...

Cloud formation characteristics of the watersoluble organic fraction (WSOC) of secondary organic aerosol (SOA) formed from the ozonolysis of alkene hydrocarbons (terpinolene, 1-methlycycloheptene and cycloheptene) are studied. Based on size-resolved measurements of CCN activity (of the pure and salted WSOC samples) we estimate the average molar volume and surface tension depression associated w...

A series of novel dissymmetric gemini cationics surfactants was synthesized by three-step reactions. The dissymmetric gemini surfactants contain a dodecanoic acid dimethylethylamine ester as the constant cationic part on one side of the hydroxypropyl center and a similar other cationic part, but with a different acid length (from octanoic to palmitic), on the other side. The critical micelle co...

A two-step acid/base-catalyzed silica gel has been aged in alcohol and water baths followed by various aprotic solvents with a wide range of surface tensions. Low temperature (CO 2) and high temperature (ethanol) aerogels were also prepared. The physical and chemical structures of gels dried from aprotic solvents were studied by a series of techniques (29Si MAS-NMR, nitrogen adsorption, SAXS, e...

We derive an expression with four adjustable parameters that reproduces well the 20×20 MiyazawaJernigan potential matrix extracted from known protein structures. The numerical values of the parameters can be approximately computed from the surface tension of water, water-screened dipole interactions between residues and water and among residues, and average exposures of residues in folded prote...