Correspondence: Koichi Jeremiah Aoki Department of Applied Physics, University of Fukui, 3-9-1 Bunkyo, Fukui, 910-0017 Japan Tel +817 7627 8665 Fax +817 7627 8750 Email [email protected] Abstract: The solubility of ferrocene in aqueous solution is known to be approximately 0.04 mmol/dm. The solubility values determined by voltammetry have been overestimated because of adsorption on electrodes...

Square-wave voltammetry was used to explore the adsorption property of cefadroxil complex with copper ions on the hanging mercury drop electrode (HMDE). By employing the adsorptive stripping voltammetric approach, a sensitive electroanalytical method for the quantitative analysis of cefadroxil antibiotic was achieved. A welldeveloped voltammetric peak was obtained in pH 10 Britton-Robinson buff...

A novel polycalconcarboxylic acid (CCA) modified glassy carbon electrode (GCE) was fabricated by electropolymerization and then successfully used to simultaneously determine ascorbic acid (AA), norepinephrine (NE) and uric acid (UA). The characterization of electrochemically synthesized Poly-CCA film was investigated by atomic force microscopy (AFM), electrochemical impedance spectroscopy (EIS)...

The voltammetric study of promethazine on multi-walled carbon nanotubes (MWNTs) coated gold electrode (MWNTs/Au) has been carried out. Promethazine can cause a sensitive anodic peak on it. In pH=4.0 phosphate buffer solution, the peak potential is 0.66 V (vs. SCE). The electrode process is adsorption-controlled, the adsorption amount is about 9.9×10 mol cm (for 1.0×10 M promethazine), and the e...

The electrooxidation of short synthetic 20-nucleotides DNA sequences with various amount of guanine molecules has been studied in a wide temperature range by square wave voltammetry and the results were compared with UV-vis and CD spectra. A twofold increase of dsDNA voltammetric peak, related to an increase in the number of electrons transferred in the guanine electrooxidation process was foun...

Adsorptive stripping voltammetry was used to prospect the adsorption property of montelukast sodium (MKST) on the hanging mercury drop electrode (HMDE). Through appointing the adsorptive stripping voltammetric (AdSV) process, a sensitive electroanalytical method for the quantitative analysis of MKST was accomplished. A well-developed voltammetric peak was obtained in pH 10 Britton-Robinson buff...

the electrocatalytic oxidation of captopril (cap) was studied by modified carbon nanotubes paste electrode in the presence of isoproterenol (ispt) using cyclic voltammetry (cv), chronoamperometry and square wave voltammetry (swv). also, the values of catalytic rate constant (k), and electron transfer coefficient (α) for cap were calculated. the mechanism of ca electrochemical behavior at the mo...

The electrochemical behavior and application of a new sensor, a silver solid amalgam paste electrode (AgSA-PE), based on the mixture of a fine silver solid amalgam powder (60:40 (w(Hg)/w(Ag))) and a suitable organic pasting liquid (Paraffin oil) in a ratio of 20:1 (w/w), was investigated in an aqueous-methanolic media (1:1). This alternative working electrode provides simple preparation and han...

A simple and highly sensitive voltammetric method was developed for the determination of isoxsuprine HCl (I) and fenoterol HBr (II) in dosage forms and biological fluids. The method is based on treatment of the two compounds with nitrous acid followed by measuring the cathodic current produced by the resulting nitroso derivatives. The voltammetric behavior was studied adopting Direct Current (D...