Isobaric vapor-liquid equilibrium measurements are reported for binary mixture of 2-Methyltetrahydrofuran and Cumene at 97.3 kPa. The data were obtained using a vapor recirculating type (modified Othmer's) equilibrium still. The mixture shows slight negative deviation from ideality. The system does not form an azeotrope. The experimental data obtained in this study are thermodynamically consist...

A new apparatus for the study of vapor-liquid or vapor-liquid-liquid equilibrium has been assembled. The apparatus, based on a static and analytical method, can perform measurements at temperatures from 185 to 320 K and pressures up to 8 MPa. The equilibrium vapor pressures of (xenon + methane) binary mixtures have been measured at seven temperatures, from 189.78 to 273.18 K, and at pressures u...

We examine ice crystal growth from water vapor at temperatures near the melting point, when surface premelting creates a quasiliquid layer at the solid/vapor interface. Recent ice growth measurements as a function of vapor supersaturation have demonstrated a substantial nucleation barrier on the basal surface at these temperatures, from which a molecular step energy can be extracted using class...

The evaporation of a liquid slab into vacuum is studied by numerical solutions of the Enskog-Vlasov equation for a fluid of spherical molecules interacting by Sutherland potential. The main aim of this work is to obtain the structure of the vapor-liquid interface in non-equilibrium conditions as well as the distribution function of evaporating molecules. The results show that the distribution f...

A coarse-grained lattice Metropolis Monte Carlo (CG-MMC) method is presented for simulating fluid systems described by standard molecular force fields. First, a thermodynamically consistent coarse-grained interaction potential is obtained numerically and automatically from a continuous force field such as Lennard-Jones. The coarse-grained potential then is used to drive CG-MMC simulations of va...

A combination of classical thermodynamics and molecular theory was used to calculate the enhancement factor (ratio of vapor-phase partial pressure to saturated vapor pressure) for liquid mercury in equilibrium with air at standard atmospheric pressure at temperatures from 0 ◦C to 40 ◦C. The enhancement factors range from 1.0025 at 0 ◦C to 1.0016 at 40 ◦C. This enhancement is too small in magnit...

Recent works on evaporation and condensation demonstrate that even these simplest irreversible processes, studied for over 100 years, are not well understood. In the case of a liquid evaporating into its vapor, the liquid temperature is constant during evaporation and the evaporation flux is governed by the heat transfer from the hotter vapor into the colder liquid. Whether liquid evaporates in...