A selective Pd probe is described, which shows fluorometric and colorimetric responses towards both Pd(2+) ions and Pd(0)-complexes with excellent sensitivity and potential application. The fluorescence quenching effect of Pd(2+) is inhibited by filling up d-orbitals after the reduction from Pd(2+) (open-shell) to Pd(0) (closed-shell).

Assembling nanoparticle-film metallic junctions with a spacing of up to tens of nanometers efficiently turned on fluorophores attached to the film from the quenching status to an intense surface plasmon-coupled emission. Benefiting from this new finding, a fluorescence biosensor was created based on the use of a biomolecule-linked plasmonic assembly as the trigger.

We propose a new strategy for fabrication of a phase-separated bicontinuous system composed of low-molecular donor and acceptor that is built up through coordination-based orientation of pyridylated fullerene on a π-conjugated zinc-porphyrin J-type assembly. This complex system exhibits extremely efficient and switchable fluorescence quenching.

Article history: Received 29.05.2012. Received in revised form 27.07.2012 Accepted 03.09.2012. The influence of sub-temperature quenching temperature on the tensile strength, hardness and toughness of 60Si2Mn steel has been studied, and the ferrite content, austenite grain size and martensite morphology of the microstructure of this steel after sub-temperature quenching analyzed. The results sh...

Article history: Received 10.9.2012 Received in revised form 10.12.2012 Accepted 10.12.2012 27SiMn steels with different original structures were zero time holding quenched after pretreatments including general quenching and normalizing, respectively, then their tensile strength and hardness were determined and also microstructures were analyzed.. The experimental results show that thus quenche...

In this paper, we introduce a new algebraic structure, called a UP-algebra (UP means the University of Phayao) and a concept of UP-ideals, UP-subalgebras, congruences and UP-homomorphisms in UP-algebras, and investigated some related properties of them. We also describe connections between UP-ideals, UP-subalgebras, congruences and UP-homomorphisms, and show that the notion of UP-algebras is a ...

objective(s):the objective of this study was to investigate the interaction of daunorubicin (dnr) and cardiac myosin (cm) and the changes in mice hearts to exhibit dnr-induced cardiotoxicity . materials and methods:the interaction between dnr and cm was expressed using fluorescence quenching at ph 4.0-9.0 and 15-37 °c. dnr-induced cardiotoxicity was studied using in vivo experiment.  forty grou...

Experiments were done to test the thesis that acrylamide and similar small molecules can penetrate into proteins on a nanosecond time scale. The approach taken was to measure the pattern of fluorescence quenching exhibited by quenching molecules differing in molecular character (size, polarity, charge) when these are directed against protein tryptophans that cover the whole range of tryptophan ...