Titanium thin layers with the same deposition conditions were deposited on glass substrates at room temperature. Different annealing temperatures namely, 400 K, 500 K and 600 K with uniform 9 cm /sec oxygen 3 flow were used to produce titanium oxide layers. The nano-structure of layers were studied using AFM and XRD methods. Optical Reflectance were studied by spectrophotometer method. Correlat...

This study presents the development of a novel calcium-oxide sorbent for carbon dioxide capture. In this work, CaO sorbent was impregnated with different molar percentage of titanium ethoxide. The sorbent prepared with 50 % of titanium ethoxide resulted in the best uptake characteristics for CO2. Compared to others, a higher BET surface area and a larger pore volume were observed. An excellent ...

Reaction products of titanium(IV) sulfate in HCl-acidic aqueous solution with the dimeric species linked through three intermolecular Ti-O-Ti bonds of the two trititanium(IV)-substituted α-Keggin polyoxometalate (POM) subunits are described. Two novel titanium(IV)-containing α-Keggin POMs were obtained under different conditions. One product was a dimeric species through two intermolecular Ti-O...

AIM The purpose of this in vitro study was to assess and compare the retention of zirconia copings luted with different luting agents onto zirconia and titanium abutments. MATERIALS AND METHODS Titanium and zirconia abutments were torqued at 35 N/cm onto implant analogs. The samples were divided into two groups: Group A consisted of four titanium abutments and 32 zirconia copings and Group B ...

A new class of complexes based on titanium(IV) bearing a bisanionic mer-tridentate N-heterocyclic carbene ligand were investigated for the copolymerization of cyclohexene oxide with CO2. Upon addition of [PPN]X' salts, all complexes were found to be active and highly selective toward the formation of poly(cyclohexene oxide-alt-carbon dioxide).

As one of the valve metals (including Ti, Al, Ta, Nb, V, Hf, W), titanium is protected by a thin titanium oxide layer which spontaneously forms on its surface when exposed to air or other oxygen containing environments. This oxide passive layer is typically 2 to 5 nm thick and is responsible for the well-documented corrosion resistance property of titanium and its alloys. Because of this and th...

The Minnesota Nano Center’s Keller Hall facility includes an atomic layer deposition (ALD) machine that is capable of depositing uniform alumina (Al2O3), hafnium oxide (HfO2), silicon dioxide (SiO2), zinc oxide (ZnO), and titanium dioxide (TiO2). ALD works by building alternate layers on a film using two different precursor gases – one usually supplying the metallic atoms and water vapor (H2O) ...

A quick and dependable technique has been developed that allows us to selectively produce anodized TiO2 in the form of nanotubes. The process employs mild chemical conditions and ambient temperature. The method can consistently produce nearly 100% surface coverage of nanotubes within 10 min of anodizing. Anodizing in relatively high pH electrolytes for 1 hour permitted us to produce nanotubes o...