[Bis(tri-methyl-sil-yl)amino](tert-butyl-imino)-thio-phospho-rane reacts in benzene with isopropyl alcohol via 1,2-addition of an (i) PrO-H bond across the P=N bond, resulting in the title compound, C13H35N2OPSSi2. In the mol-ecule, the P atom possesses a distorted tetra-hedral environment involving two N atoms from (Me3Si)2N- and (t) BuNH- groups, one O atom from an (i) PrO group and one S ato...

The catalytic activity of the iron(II) C-scorpionate complexes [FeCl2{HC(pz)3}] 1 (pz = pyrazol-1-yl) and [FeCl2{HOCH2C(pz)3}] 2, and of their precursor FeCl2·2H2O 3, towards cyclohexane oxidation with tert-butyl hydroperoxide was evaluated and compared in different media: acetonitrile, ionic liquids (1-butyl-3-methylimidazolium hexafluorophosphate, [bmim][PF6], and 1-butyl-3-methylimidazolium ...

Some 1,2,4-triazole derivatives were titrated potentiometrically with tetrabutylammonium hydroxide in four non-aqueous solvents such as isopropyl alcohol, N,N-dimethylformamide (DMF), tert-butyl alcohol and acetonitrile, and the half-neutralization potential values and the corresponding pKa values were determined for all cases.

An efficient sequential four-component reaction of chromone carbaldehydes, Meldrum's acid, 4-hydroxyl coumarin or 6-methyl-4-hydroxyl-pyrone and primary alcohols is reported which leads to 5a-i in aqueous media. Replacing the primary alcohol with isopropyl alcohol and tert-butyl alcohol results in different products 10 and 11. The environmentally friendly features, good to high yields and easy ...

The reactivity of microsolvated fluoride ions, F (CH3OH)0–2, with methyl, ethyl, n-propyl, and t-butyl bromide is evaluated over a broad range of temperatures. Significant decreases in reactivity are observed as either solvation or temperature increases. Increasing solvation increases sensitivity to the reaction barrier as revealed by a larger temperature dependence. These reactions are dominat...

We previously showed that barley sprout extract (BSE) prevents chronic alcohol intake-induced liver injury in mice. BSE notably inhibited glutathione (GSH) depletion and increased inflammatory responses, revealing its mechanism of preventing alcohol-induced liver injury. In the present study we investigated whether the antioxidant effect of BSE involves enhancing nuclear factor-erythroid 2 rela...

Addition of an excess of t-butyl isocyanide to solid Mo2 (0, CCF3 )4 or MO?_ (0, CMe)4 gives (t-BuNC), Mo(Oz CCF3 )* or (t-BuNC), Mo(Oz CMe), , respectively. The quadruple bond in K4 MO* Cl8 or Cl4 MO, (n-Bus P)4 also can be cleaved by an excess of t-butyl isocyanide to yield (t-BuNC), MoCl, _ The anionic ligands can be exchanged with ammonium hexafluorophosphate in presence of excess t-BuNC to...

BACKGROUND Aster tataricus L. f. is used as a traditional Chinese drug to relieve cough and asthma symptoms and to eliminate phlegm. However, Aster tataricus L. f. possesses toxicity, and little systematic research has been conducted on its toxic effects in the laboratory. METHODS AND MATERIALS The acute group was administered 75% alcohol extract of Aster tataricus L. f. in a single dose. A s...

Pyrolysis of diethyl (C4), di-n-propyl (C6), di-isopropyl (C6) and di-n-butyl (C8) ethers were studied in a jet-stirred reactor between 720 1140 K, at 10 atm with an initial ether mole fraction 0.1%. Major common pyrolysis products observed to be CO, CH4, H2, C2H4. All produced the n/2 alcohol olefin as molecular reaction small extent. Under conditions atm, hydrogen abstraction reactions by H a...

background: methyl tert -butyl ether (mtbe) has been commercially used as an octane enhancer to replace tetraethyl lead in gasoline since 1979. the high mobility, water solubility, and resistance to natural attenuation associated with mtbe may re­sult in contamination of ground and surface waters. in this investigation the degradation of aqueous mtbe at relatively high concentrations was studie...