Enzyme efficiency was investigated in the lipase-catalyzed hydrolysis of canola oil in supercritical carbon dioxide (SCCO2). Immobilized lipase from Mucor miehie (Lipozyme IM) was used as the catalyst and the results showed that enzyme efficiency dropped at high pressures indicating a possible change in enzyme microstructure. Therefore, scanning electron microscopy (SEM) was used...

The total oil content of soyflakes, canola seed and wetmilled corn germ were determined by analytical supercritical fluid extraction (SFE) with carbon dioxide as the extraction solvent. Results obtained by SFE were in excellent agreement with those obtained by a conventional Soxhlet technique with organic solvents. The analyticalscale SFE technique yielded average means within one standard devi...

The MODAR process uses supercritical water, heated above 374OC and pressurized above 220 atm, as a medium for the rapid and complete oxidation of organic compounds to carbon dioxide, water and inorganic salts. The destruction efficiencies achieved exceed 99.99% for a wide range of compounds including chlorinated solvents and PCB’s. The exothermic oxidation reaction produces sufficient energy to...

In recent years, Integrated Gasification Combined Cycle Technology (IGCC) has been gaining steady popularity for use in clean coal power operations with carbon capture and sequestration. Great efforts have been continuously spent on investigating various ways to improve the efficiency and further reduce the greenhouse gas (GHG) emissions of such plants. This study focuses on investigating two a...

Vaccinium meridionale Swartz (Mortiño or Colombian blueberry) is one of the Vaccinium species abundantly found across the Colombian mountains, which are characterized by high contents of polyphenolic compounds (anthocyanins and flavonoids). The supercritical fluid extraction (SFE) of Vaccinium species has mainly focused on the study of V. myrtillus L. (blueberry). In this work, the SFE of Morti...

The purpose of this work is to provide a complete study of the influence of operational parameters of the supercritical carbon dioxide assisted extraction (SC CO2E) on yield of wedelolactone from Wedelia calendulacea Less., and to find an optimal combination of factors that maximize the wedelolactone yield. In order to determine the optimal combination of the four factors viz. operating pressur...

Due to an increase of the nuclear power plant, radioactive waste is also increasing trend and due to the large amount of radioactive waste disposal costs also increase. Decontamination of soil contamination is depending on the soil characteristics and environmental factor, so single decontamination method is difficult for effective decontamination. We need innovative method to decontamination, ...

A response surface methodology was applied to optimize the variables affecting the supercritical fluid carbon dioxide extraction of oil from the fruit of Gardenia jasminoides using the Box-Behnken design. The optimum extraction parameters were an extraction temperature of 49.94 °C, an extraction pressure of 29.89 MPa and an extraction time of 93.82 min. Through a GC/MS analysis, we revealed 16 m...

Heat transfer of supercritical carbon dioxide cooled in circular tubes was investigated experimentally. The effect of mass flux, pressure, and heat flux on the heat transfer coefficient and pressure drop was measured for four horizontal cooling tubes with different inner diameters ranging from 1 to 6 mm. The radial distribution of the thermophysical properties (i.e. specific heat, density, ther...

Aliphatic alcohols of chain lengths of 24–34 carbons have been found to be beneficial in treating hypercholesterolemia. Approximately 40% of beeswax is long-chain esters which can be transesterified in supercritical carbon dioxide to give these alcohols and fatty acid methyl esters. The methanolysis reaction was catalyzed by an immobilized lipase from Candida antarctica in flowing supercritical...