نتایج جستجو برای: supercritical carbon dioxide
تعداد نتایج: 321349 فیلتر نتایج به سال:
Isolation and structural characterization of the elusive 1:1 adduct of hydrazine and carbon dioxide.
A solid hydrazine was isolated as a crystalline powder by reacting aqueous hydrazine with supercritical CO(2). Its structure determined by single crystal X-ray diffraction shows a zwitterionic form of NH(3)(+)NHCO(2)(-). The solid hydrazine is remarkably stable but is as reactive as liquid hydrazine even in the absence of solvents.
In the present investigation efforts have been made to synthesis polyvinyl pyridine (PvPy) /C60 conjugates through 2, 2-azobisisobutyronitrile (AIBN) initiated insitu polymerization of PvPy in scCO2.The process of synthesis was monitored under different reaction conditions ranging 1200-1800psi, 60-90 oC over 6 hours. The progress of polymerization was monitored rheoviscometrically. The concentr...
Colloidal carbon spheres were synthesized by the carbonization of squalane, a nonvolatile hydrocarbon solvent, in supercritical carbon dioxide. Precise pressure modulation of the fluid medium led to size controlled growth of carbon spheres ranging from 300 to 1500 nm in diameter. This unique synthetic approach of carbonizing a hydrocarbon suspension in supercritical fluid is found to suppress a...
The gas-like mass transfer properties and liquid-like solvation characteristics of supercritical fluid make it a promising medium in performing extractory and chromatographic separations, i.e., supercritical fluid extraction (SFE) and supercritical fluid chromatography (SFC), respectively. The tunable solvation properties of supercritical carbon dioxide not only improve SFE's efficiency and spe...
Electrodeposition is a widely used materials-deposition technology with a number of unique features, in particular, the efficient use of starting materials, conformal, and directed coating. The properties of the solvent medium for electrodeposition are critical to the technique's applicability. Supercritical fluids are unique solvents which give a wide range of advantages for chemistry in gener...
Synthesis of poly(2,2,2-trifluoroethyl methacrylate) by supported ATRP was investigated in supercritical carbon dioxide using a copper salt ligated to a polymeric ligand immobilised onto silica; after polymerisation, fluorinated polymers with well defined molecular weight and low polydispersity were obtained.
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