Recent advance in understanding the supercritical state posits the existence of a new line above the critical point separating two physically distinct states of matter: rigid liquid and non-rigid gas-like fluid. The location of this line, the Frenkel line, remains unknown for important real systems. Here, we map the Frenkel line on the phase diagram of supercritical iron using molecular dynamic...

a new correlation function for the calculation of viscosity for five typical supercritical gases is presented using the rainwater-friend and modified enskog theory. it is shown that by using accurate value for the thermal pressure and co-volume in the modified enskog theory, this correlation function is suitable for calculation of the viscosity of supercritical gases, without any density and te...

The esterification reaction of phthalic anhydride with methanol was performed at different temperatures in a continuous flow glass microreactor at pressures up to 110 bar and using supercritical CO(2) as a co-solvent. The design is such that supercritical CO(2) can be generated inside the microreactor. Substantial rate enhancements were obtained, viz. a 53-fold increase was obtained at 110 bar ...

Recently, Supercritical fluids have been used in material synthesis and processing because of their special properties such as high diffusivity, low viscosity, and low surface tension. Supercritical carbon dioxide is the most attractive because it is non-toxic, non-flammable, and has moderate critical temperature and critical pressure. Moreover, and can also swell most polymers. In this study, ...

Hydrogen is an important chemical in many industries and it is expected to become one of the major fuels for energy generation in the future. Unfortunately, hydrogen does not exist in its elemental form in nature and therefore has to be produced from hydrocarbons, hydrogen-containing compounds or water. Above its critical point (374.8C and 22.1MPa), water has lower density and viscosity, and a ...

Symmetry and monotonicity properties of solitary water-waves of positive elevation with supercritical values of parameter are established for an arbitrary vorticity. The proof uses the detailed knowledge of asymptotic decay of supercritical solitary waves at infinity and the method of moving planes.

T R I B O L O G Y & L U B R I C A T I O N T E C H N O L O G Y W W W . S T L E . O R G wide range of approaches have been undertaken to determine how to reduce emissions from automotive engines. in a previous TLT article, the development of the homogeneous charge compression ignition (hCCi) engine was discussed. When used in place of a conventional gasoline engine, an hCCi engine can produce a 1...

The solvation shell dynamics of supercritical water is analyzed by molecular dynamics simulation with emphasis on its relationship to the translational and rotational dynamics. The relaxation times of the solvation number (tau S), the velocity autocorrelation function (tau D), the angular momentum correlation function (tau J), and the second-order reorientational correlation function (tau 2R) a...

Supercritical fluids play a significant role in elucidating fundamental aspects of liquid matter under extreme conditions. They have been extensively studied at pressures and temperatures relevant to various industrial applications. However, much less is known about the structural behaviour of supercritical fluids and no structural crossovers have been observed in static compression experiments...

Supercritical carbon dioxide has replaced many liquid organic solvents in industry due to its tunable solvent properties, environmental friendliness, and easily achievable critical parameters. The unique properties of supercritical fluids in general, such as gas-like diffusivity and zero surface tension, make them particularly applicable to the field of conservation. This presentation reports o...