Electron spin resonance (ESR) spin trapping was utilized to investigate the generation of free radicals from oxidation of sodium sulfite, nickel(II) sulfite, and nickel subsulfide (Ni3S2) by ambient oxygen or H2O2 at pH 7.4. The spin trap used was 5,5-dimethyl-1-pyrroline-N-oxide (DMPO). Under ambient oxygen, a solution of sodium sulfite alone generated predominantly sulfur trioxide anion radic...

An efficient electrocatalytic biosensor for sulfite detection was developed by co-immobilizing sulfite oxidase and cytochrome c with polyaniline sulfonic acid in a layer-by-layer assembly. QCM, UV-Vis spectroscopy and cyclic voltammetry revealed increasing loading of electrochemically active protein with the formation of multilayers. The sensor operates reagentless at low working potential. A c...

A Chan–Lam-type C–S coupling reaction using sodium aryl sulfinates has been developed to provide diaryl thioethers in up 92% yields the presence of a copper catalyst and potassium sulfite. Both electron-rich electron-poor diverse organoboron compounds were tolerated for synthesis heteroaryl dithioethers. The mechanistic study suggested that sulfite was involved deoxygenation sulfinate through r...

Isolated sulfite oxidase deficiency is a very rare autosomal recessive disorder associated with metabolism of sulfur containing amino acids. A 4-month-old girl with intractable seizures and feeding difficulty diagnosed as isolated sulfite oxidase deficiency is presented.

Colorimetric recognition and sensing of sulfite by melamine-modified gold nanoparticle is reported, using Tris-HCl as the operating buffer. Furthermore, indirect determination of hypochlorite is accomplished by its oxidation of sulfite.

continue on reverse if necessary and identify by block number) The corrosion mechanisms and behavior of a P-130x graphite fiber reinforced 6063 aluminum composite laminate were udied. Electrochemical and total immersion tests were performed on the composite in 3.5% sodium chloride and 5.0% >dium sulfate solutions. The effects of pH, the presence of sulfite ions, various heat treatments, and ele...

Air pollutants are supposed to modulate physiological responses of alveolar macrophages (AM). This study was addressed to the question whether at neutral pH sulfur(IV) species in comparison to sulfur(VI) species cause AM to release proinflammatory mediators and which pathways are involved in their generation. Supernatants obtained from canine AM treated with sulfite (0.1 mM to 2 mM) enhanced th...