The enthalpy of hydrolysis of the 3’-bond of several cyclic 3’,5’-nucleotides and of the 2’-bond of several cyclic 2’,3’nucleotides has been measured calorimetrically. In each case, the enthalpy was indicative of a high energy bond, although values for different compounds varied from -7.7 to 14.1 kcal mole-‘. The enthalpy of hydrolysis of the cyclic 3’,5’-nucleotides, but not that of the cyclic...

Constitutive equations are derived for enthalpy recovery in polymeric glasses after thermal jumps. The model is based on the theory of cooperative relaxation in a version of the trapping concept. It is demonstrated that some critical temperature Tcr and some critical degree of crystallinity fcr exist in a semicrystalline polymer above which the energy landscape becomes homogeneous and structura...

research works proposed that radical scavenging activity of flavonoids is due to ring b, andthe remaining part of the molecule can be disregarded. thus the objective of this work is toobserve whether hydroxytoluenes account the radical scavenging activity of flavonoid and toestablish structural requirements for their activity (as they showed appreciable activity) andelucidate a comprehensive me...

The interaction of spermine and its analogue, 1-naphthyl acetyl spermine with four double stranded DNA polynucleotides has been studied to understand the structural and thermodynamic basis of the binding. The efficacy and specificity of DNA binding of this analogue has not yet been revealed. The energetics of the interaction was studied by isothermal titration calorimetry and differential scann...

The effect of temperature, pH, free [Mg(2+)], and ionic strength on the apparent equilibrium constant of arginine kinase (EC 2.7.3.3) was determined. At equilibrium, the apparent K' was defined as [see text] where each reactant represents the sum of all the ionic and metal complex species. The K' at pH 7.0, 1.0 mM free [Mg(2+)], and 0. 25 M ionic strength was 29.91 +/- 0.59, 33.44 +/- 0.46, 35....

We derived one-fluid equations based on a relativistic two-fluid approximation of e pair plasma and electron-ion plasma to reveal the specific relativistic nature of their behavior. Assuming simple condition on the relativistic one-fluid equations, we propose generalized relativistic magnetohydrodynamic (RMHD) equations which satisfy causality. We show the linear analyses of these equations reg...

A steady-state one-dimensional axisymmetric numerical model of a mechanical seal in two-phase flow is presented. In this work non-linear thermal implemented using coupled (monolithic) approach, linking the fluid film and sealing rings. It solved for temperature fields solids, heat fluxes between fluids enthalpy fluid, vapor mass fraction, Newtons method. The novelty approach lies 1) coupling 2)...

The enthalpy of hydrolysis of the 3’-bond of several cyclic 3’,5’-nucleotides and of the 2’-bond of several cyclic 2’,3’nucleotides has been measured calorimetrically. In each case, the enthalpy was indicative of a high energy bond, although values for different compounds varied from -7.7 to 14.1 kcal mole-‘. The enthalpy of hydrolysis of the cyclic 3’,5’-nucleotides, but not that of the cyclic...