TiO2–FeZn nanocatalyst combined with sonolysis were used to activate peroxymonosulfate (PMS) as a highly efficient advanced oxidation process (US/TiO2–FeZn/PMS) for the decoloration of orange II dye (OII) and real textile wastewater. The characterization as-synthesized NPs was performed by SEM, FTIR, EDX XRD analyses. Optimal experimental conditions operational parameters obtained: pH = 3, 15 m...

Here, the magnetic Fe3O4@SiO2/PAEDTC@MIL-101 (Fe) with a new core-shell structure was synthesized, and its sonophotocatalytic properties were evaluated for acid red 14 (AR14) degradation. Particle characterizations determined by scanning electron microscope (SEM), transmission microscopy (TEM), X-ray powder diffraction (XRD), vibrating-sample magnetometer (VSM), analysis results offered an exce...

The behavior of Pu(iv) and Pu(iii) was investigated in aqueous nitric solutions under ultrasound irradiation (Ar, 20 kHz). In the absence of anti-nitrous reagents, ultrasound has no effect on Pu(iv), while Pu(iii) can be rapidly oxidized to Pu(iv) due to the autocatalytic formation of HNO(2) induced by HNO(3) sonolysis. In the presence of anti-nitrous reagents (sulfamic acid or hydrazinium nitr...

The sonolytic degradation of ozone (O3) was investigated in both closed and open continuous-flow systems to examine effects of mass transfer on chemical reactivity in the presence of ultrasound. Degradation of O3 followed apparent first-order kinetics at frequencies of both 20 and 500 kHz in all the systems. Degassing of O3 was observed at 20 kHz due to the effects of rectified diffusion and la...

Carrageenan as an abundant natural carbohydrate could be used as a representative material instead of synthetic polymers. In this work, the degradation of κ-Carrageenan by means of ultrasound irradiation at a frequency of 24 kHz and its combination with heterogeneous Titanium dioxide, followed by a photocatalytic process was investigated. The scission of carrageenan chains induced by a high int...

Ultrasonic irradiation has been shown to effectively degrade perfluorinated chemicals (PFCs) such as perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) in aqueous solution. Reduced PFC sonochemical degradation rates in organic-rich groundwater taken from beneath a landfill, however, testify to the negative kinetic effects of the organic groundwater constituents. In this study, the P...

Ultrasound treatment was used to study the decrease of the granulometry of graphite, due to the cavitation, which allows the erosion by separating grains. At a smaller scale, cavitation bubble implosion tears apart graphite sheets as shown by HRTEM, while HO(*) and H(*) radicals produced from water sonolysis, generate oxidative and reductive reactions on these sheet fragments. Such reactions fo...

In the last decade, nanobiotechnology has evolved rapidly with an extensive impact on biomedical area. In order to improve bioavailability and minimize adverse effects, drug delivery systems based on magnetic nanocomposites are under development mainly for cancer imaging and antitumor therapy. In this regard, pH sensitive core-shell magnetic nanoparticles (NPs) with accurate controlled size and...