Iron(III) oxide shows a polymorphism, characteristic of existence of phases with the same chemical composition but distinct crystal structures and, hence, physical properties. Four crystalline phases of iron(III) oxide have previously been identified: α-Fe2O3 (hematite), β-Fe2O3, γ-Fe2O3 (maghemite), and ε-Fe2O3. All four iron(III) oxide phases easily undergo various phase transformations in re...

A mild, green and highly efficient route for regio-selective amination of oxiranes was developed via incorporation of Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) cations onto the surface of hydroxyapatite-encapsulated γ-Fe2O3 nanoparticles (γ-Fe2O3@HAp). Among six magnetically recoverable catalytic systems denoted as [γ-Fe2O3@HAp-MII], the catalyst in which M designated as Fe(II) showed t...

A facile synthesis of Ag2S-hollow Fe2O3 nanocomposites with NIR photoluminescence was firstly demonstrated by the sulfidation of Ag-Fe2O3 core-shell nanoparticles. Characteristic morphology transformations along with color changes were recorded and a mechanism was proposed for the sulfidation process, which can provide new possibilities to fabricate other complex nanostructures.

Superparamagnetic iron oxide nanoparticles (SPIONs) with multifunctional properties have shown great promise in theranostics. The aim of our work was to compare the effects of SPIONs on the fluidity and phase transition of the liposomal membranes prepared with zwitterionic phosphatidylcholine lipids. In order to study if the surface modification of SPIONs has any influence on these membrane pro...

ABSTRACT The functionalization of silica-coated Fe3O4 magnetic nanoparticles (Fe3O4@SiO2) using chlorosulfonic acid were afforded sulfonic acid-functionalized magnetic Fe3O4 nanoparticles (Fe3O4@SiO2-SO3H) that can be applied as an organic-inorganic hybrid heterogeneous catalyst. The used Fe3O4 magnetic nanoparticles are 18-30 nm sized that was rapidly functionalized and can be used as catalyst...

X-ray photoelectron (XPS) and Raman spectroscopic techniques have been used to study the influence of the annealing ambient (N2, Ar and H2) of nearly monodispersed Fe2O3 nanoparticles (mean size = 3.2 ± 1 nm) on the growth of carbon nanotubes by microwave plasma chemical vapour deposition. XPS characterization of the catalytic templates reveals that a N2 ambient reduces sintering of the Fe2O3 n...

The changes of the phase composition of iron oxide samples prepared by solgel method using single precursor both for nanoparticles and the matrix were studied by x-ray diffraction. Obtained data were analyzed by an approach using the Debye formula which is suitable for the size of particles up to about 10 nm. The phase composition of the nanoparticles was described by a core-shell model corresp...

Iron oxides are extensively investigated as anode materials for lithium-ion batteries (LIBs) because of their large specific capacities. However, they undergo huge volume changes during cycling that result in anode pulverization and loss of electrical connectivity. As a result, the capacity retention of the iron oxide anodes is poor and should be improved for commercial applications. Herein, we...

Coupling ultrasmall Fe2O3 particles (~4.0 nm) with the MoS2 nanosheets is achieved by a facile method for high-performance anode material for Li-ion battery. MoS2 nanosheets in the composite can serve as scaffolds, efficiently buffering the large volume change of Fe2O3 during charge/discharge process, whereas the ultrasmall Fe2O3 nanoparticles mainly provide the specific capacity. Due to bigger...