In this study, chemical transformations of benzyl ester of О-(phenyl-2-acetamido-2,3-dideoxy-1-thio-β-d-glucopyranoside-3-yl)-d-lactoyl-l-alanyl-d-isoglutamine (SPhMDPOBn) on the fumed silica surface were examined, and the surface complex structure was characterized by temperature-programmed desorption mass spectrometry (TPD-MS), infrared spectroscopy (FTIR) and electrospray ion trap mass spect...

Mild and applicable synthesis of mono-, bis-, and spiro- perimidines is demonstrated in high yields via the condensation of 1,8-diaminonaphthalene and aldehydes or ketones in the presence of sulfamic acid as a green and highly efficient catalyst. This environmentally benign and clean synthetic pathway offers several advantages, such as high yields, short reaction times and easy work-up procedure.

Superprotonic conductivity, utilizing MOFs embedded with a moderately acidic guest—zwitterionic sulfamic acid (HSA)—was demonstrated by Myoung Soo Lah et al. in their Research Article (e202302376). HSA not only acted as proton source, but also proton-conducting medium. The MOFs, which had been filled high quantities of using sustained concentration gradient method, exhibited impressive superpro...

the kinetics of the de complexation by hydroxyl ions of some pervanadyl, molybdate and tungstate amionocarboxylate complexes have been studied spectrophotometrically by means of a stopped flow technique. the chelate groups used were the iminodiacetic acid (ida), ethylenediarnine-n,n' -diacetic acid (edda), nitrilotriacetic acid (nta) and ethylene diamine-n,n,n' ,n'-tetraacetic ac...

sulfonic acid-based precursors (sap) play an important role in tailoring mesoporous silica’s and convert them to a solid acid catalyst with a bronsted-type nature. these kinds of solid acids contribute to sustainable and green chemistry by their heterogeneous, recyclable, and high efficiency features. therefore, knowing the properties and reactivity of saps can guide us to manufacture a sulfona...

nano silica sulfuric acid as a solid acid, was described to be an effective catalyst for one-pot three-component reaction of kojic acid, aryl aldehydes and indoles for the preparation of 2-substituted aryl (indolyl) kojic acid derivatives. the catalyst was prepared by combination of chlorosulfonic acid to nano silica gel. the size of nanoparticles were observed with sem.all prepared compounds w...

Diatom cell walls are regarded as a paradigm for controlled production of nanostructured silica, but the mechanisms allowing biosilicification to proceed at ambient temperature at high rates have remained enigmatic. A set of polycationic peptides (called silaffins) isolated from diatom cell walls were shown to generate networks of silica nanospheres within seconds when added to a solution of si...

Formation of non bonded organic layer around inorganic particles like iron sulfide and zeolites, was hypothesized as starting point for one of the possible mechanisms of the origin of life on earth. In this study, the general circumstances needed for creation of such organic layer was investigated. An aliphatic hydrocarbon (hexane), an aromatic hydrocarbon (toluene), an alcohol (n-octanol) and ...

formation of non bonded organic layer around inorganic particles like iron sulfide and zeolites, was hypothesized as starting point for one of the possible mechanisms of the origin of life on earth. in this study, the general circumstances needed for creation of such organic layer was investigated. an aliphatic hydrocarbon (hexane), an aromatic hydrocarbon (toluene), an alcohol (n-octanol) and ...