Valence-band and conduction-band edges of ultrathin oxides SiO2, HfO2, Hf0.7Si0.3O2, and Al2O3 grown on silicon and their shifts upon sequential metallization with ruthenium have been measured using synchrotronradiation-excited x-ray, ultraviolet, and inverse photoemissions. From these techniques, the offsets between the valence-band and conduction-band edges of the oxides, and the ruthenium me...

Die meta C–H-Funktionalisierung durch Ruthenium-katalysierte σ-Bindungsaktivierung hat sich als nützliches Werkzeug zum Knüpfen distaler C–C-Bindungen erwiesen. Aufgrund der begrenzten Anzahl von mechanistischen Studien ist jedoch kein klares Verständnis des Hintergrunds Regioselektivität und vollständigen Reaktionsmusters vorhanden. Hier präsentieren wir systematische computerchemische zur Rut...

We have recently demonstrated that complexation with (η(6)-arene)Ru(II) fragments confers 4-anilinoquinazoline pharmacophores a higher potential for inducing cellular apoptosis while preserving the highly inhibitory activity of 4-anilinoquinazolines against EGFR and the reactivity of the ruthenium centre to 9-ethylguanine (Chem. Commun., 2013, 49, 10224-10226). Reported herein are the synthesis...

Chiral ruthenium olefin metathesis catalysts can perform asymmetric ring-closing reactions in > or = 90% ee with low catalyst loadings. To illustrate the practicality of these reactions and the products they form, an enantioselective total synthesis of 5-epi-citreoviral was completed by using an asymmetric ring-closing olefin metathesis reaction as a key step early in the synthesis. All of the ...

Primary alcohols can be coupled with secondary benzylic alcohols by an air-stable catalytic system involving terpyridine ruthenium or iridium complexes.

The slow dissociation of DNA threading intercalators makes them interesting as model compounds in the search for new DNA targeting drugs, as there appears to be a correlation between slow dissociation and biological activity. Thus, it would be of great value to understand the mechanisms controlling threading intercalation, and for this purpose we have investigated how the length of the bridging...

Ionic liquids are a stabilizing medium for the in situ synthesis of ruthenium nanoparticles. Herein we show that the addition of molecular polar solutes to the ionic liquid, even in low concentrations, eliminates the role of the ionic liquid 3D structure in controlling the size of ruthenium nanoparticles, and can induce their aggregation. We have performed the synthesis of ruthenium nanoparticl...

An EGTA (ethanedioxybis(ethylamine)tetra-acetic acid)-quench technique was developed for measuring initial rates of (45)Ca(2+) transport by rat liver mitochondria. This method was used in conjunction with studies of Ca(2+)-stimulated respiration to examine the mechanisms of inhibition of Ca(2+) transport by the lanthanides and Ruthenium Red. Ruthenium Red inhibits Ca(2+) transport non-competiti...

purpose : to assess the results of brachytherapy in patients with recurrent or incomplete excised conjunctival squamous cell carcinoma (scc) and malignant melanoma. methods : three patients underwent brachytherapy of one eye and one patient underwent brachytherapy of both eyes with ruthenium-106 (ru-106) plaques, all of them had a history of incomplete resection or recurrence of the tumor after...

ru/al2o3 catalysts were prepared by conventional incipient wetness impregnation as well as colloid deposition of rucl3 precursor via in situ reduction with ethylene glycol (polyol) method on alumina support. the samples were characterized by tem, xrd and tpr techniques. the catalytic performance tests were carried out in a fixed-bed micro-reactor under different operating conditions. ethylene g...