A high-resolution gas-phase spectrum of a molecular absorption band around 604 nm is assigned as due to an electronic transition of a nonlinear C6H4 1 planar species starting from its A9 electronic ground state. The spectrum is observed in direct absorption by cavity ringdown spectroscopy through a supersonic planar discharge through a mixture of acetylene in helium. The spectrum has a clear ro...

The 3psigma(u)D (3)Sigma(u) (+) Rydberg state of N(2) is studied experimentally using two high-resolution spectroscopic techniques. First, the forbidden D (3)Sigma(u) (+)-X (1)Sigma(g) (+) transition is observed for the first time via the (0,0) band of (14)N(2) and the (1,0) band of (15)N(2), using 1 extreme-ultraviolet +1 ultraviolet two-photon-ionization laser spectroscopy. Second, the Rydber...

C6H5SO2 radicals were produced upon irradiation of three flowing mixtures: C6H5SO2Cl in N2, C6H5Cl and SO2 in CO2, and C6H5Br and SO2 in CO2, with a KrF excimer laser at 248 nm. A step-scan Fourier-transform spectrometer coupled with a multipass absorption cell was employed to record the time-resolved infrared (IR) absorption spectra of reaction intermediates. Two transient bands with origins a...

In this paper we show how rotational bands of resonances can be described by using trajectories of poles of the scattering amplitude in the complex angular momentum plane: each band of resonances is represented by the evolution of a single pole lying in the first quadrant of the plane. The main result of the paper consists in showing that also the antiresonances (or echoes) can be described by ...

Rotational diffusion of cytochrome oxidase in the inner membrane of rat liver mitochondria was measured by detecting the decay of absorption anisotropy after photolysis of the heme a3.CO complex by a vertically polarized laser flash. As in previous experiments with beef heart mitochondria (Kawato, S., Sigel, E., Carafoli, E., and Cherry, R. J. (1980) J. Biol. Chem. 255, 5508-5510), co-existence...

Over 250 rotational transitions of the internal rotor methyl formate (HCOOCH3 ) in its ground ( V1 = 0) degenerate (E) torsional substate have been measured in the millimeter-wave spectral region. These data and a number of E-state lines identified by several other workers have been analyzed using an extension of the classical principal-axis method in the high barrier limit. The resulting rotat...

The Doppler-free two-photon excitation spectrum of the vibrationless A ‘Btc jt ‘A, transition of difluorodiaxirine (F&N,) has been recorded with a resolution of 15 MHz using a cw single-mode dye laser coupled to an external concentric resonator. The asymmetric rotor spectrum has been analysed and more than 350 lines randomly selected from all five branches were assigned in order to fit the grou...

We demonstrated lasing in two-dimensional trivalent network structures with short-range order. Despite the lack of translational and rotational symmetries, such structures possess a large isotropic photonic bandgap. Different from those of a photonic crystal, the band-edge modes are spatially localized and have high quality factor.

We present a review of the mean-field approaches describing superdeformed states, which are currently used and/or being developed. As an example, we discuss in more details the properties of superdeformed A∼60 nuclei, and present results of calculations for the rotational band in the doubly magic superdeformed nucleus S.