In this work, the interaction of protonated amino acids with a chromene bearing a fused 18-crown-6 ether moiety was studied by UV-vis and NMR spectroscopy. Initial closed forms of the chromene form monotopic 1 : 1 complexes, the ammonium group being localized inside the crown ether cavity. UV-irradiation leads to transformation of the ring-closed species into the ring-opened form. Depending on ...

In a quantum ring connected with two external leads the spin properties of an incoming electron are modified by the spin-orbit interaction resulting in a transformation of the qubit state carried by the spin. The ring acts as a one qubit spintronic quantum gate whose properties can be varied by tuning the Rashba parameter of the spin-orbit interaction, by changing the relative position of the j...

Iodinated X-ray contrast agents are considered to be nondegradable by microorganisms. The decomposition of the ionic X-ray contrast agents Diatrizoate (3,5-di(acetamido)-2,4,6-triiodobenzoic acid) and Iodipamide (3,3'-adipoyl-diimino-di(2,4,6-triiodobenzoic acid) and related triiodinated benzoates (Acetrizoate [3-acetylamino-2,4, 6-triiodobenzoic acid] and Aminotrizoate [3-amino-2,4, 6-triiodob...

construction of various heterocyclic rings. The reactions of pyrylium or thiopyrylium salts, six-membered cationic heteroaromatics containing an oxygen or sulfur atom, with nitrogen-containing nucleophiles to afford a variety of nitrogen-containing heterocyclic compounds provide one of the most effective examples of the ring transformation. Sixmembered heterocycles such as pyridines, quinolines...