نتایج جستجو برای: rare earth metal

تعداد نتایج: 514314  

Journal: :Dalton transactions 2015
Xiufang Wang Xuebing Leng Yaofeng Chen

Four mono(boratabenzene) rare-earth metal dialkyl complexes, [(3,5-Me2-C5H3BR)Ln(CH2SiMe3)2(THF)] (1: R = NEt2, Ln = Sc; 2: R = NEt2, Ln = Lu; 3: R = Ph, Ln = Sc; 4: R = Ph, Ln = Lu), were synthesized efficiently via a one-pot strategy with Li[3,5-Me2-C5H3BR] (R = NEt2, Ph), LnCl3(THF)x (Ln = Sc, x = 3; Ln = Lu, x = 0), and LiCH2SiMe3. The solid-state structures of 1 and 2 were determined by si...

2016
Valentina Bisogni Sara Catalano Robert J. Green Marta Gibert Raoul Scherwitzl Yaobo Huang Vladimir N. Strocov Pavlo Zubko Shadi Balandeh Jean-Marc Triscone George Sawatzky Thorsten Schmitt

The metal-insulator transition and the intriguing physical properties of rare-earth perovskite nickelates have attracted considerable attention in recent years. Nonetheless, a complete understanding of these materials remains elusive. Here we combine X-ray absorption and resonant inelastic X-ray scattering (RIXS) spectroscopies to resolve important aspects of the complex electronic structure of...

Journal: :Journal of the Magnetics Society of Japan 1998

Journal: :Journal of the Japan Society of Powder and Powder Metallurgy 2019

Journal: :Nature Physics 2023

Long viewed as passive elements, antiferromagnetic materials have emerged promising candidates for spintronic devices due to their insensitivity external fields and potential high-speed switching. Recent work exploiting spin orbital effects has identified ways electrically control probe the spins in metallic antiferromagnets, especially non-collinear or non-centrosymmetric structures. The rare-...

Journal: :Organometallics 2023

Rare-earth metal carboryne complexes LRE(C2B10H10)(thf)n [n = 2, RE Y (1a), Er (1b); n 1, (2); L 2-(2,5-Me2C4H2N)C6H4NC(Ph)N(2,6-iPr2C6H3)] were synthesized in good yields via either an alkane elimination reaction of rare-earth dialkyls LRE(CH2SiMe3)2 with 1 equiv o-carborane (o-C2B10H12) THF or a salt metathesis yttrium dichloride LYCl2(thf)3 Li2C2B10H10 toluene. They could be viewed as class ...

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