Monodisperse cobalt nanoparticles are synthesized via a high-temperature thermal decomposition method in the presence of oleic acid and triphenylphosphine. The as-synthesized nanoparticles are stable against further deep oxidation when they are kept in heptane .C7H16/. Time-dependent XPS studies indicate that oxidation of the as-synthesized cobalt nanoparticles in air is slow. The valence chang...

In this study we investigated the optical and electronic properties of cobalt doped Zinc Oxide (ZnO) nanoparticles (quantum dots) fabricated by a precipitation method. We observed significant reduction in ZnO nanoparticle diameter as we increased the percentage of cobalt. UV-VIS absorption measurement show a systematic increase in bandgap from 3.40 eV to 3.69 eV as the cobalt percentage is incr...

The morphology and magnetic properties of diblock copolymer templated ferrimagnetic cobalt oxide nanoparticles are reported. Ring opening metathesis polymerization (ROMP) was used to synthesize a novel cobalt diblock copolymer, where cobalt is directly attached to the polymer chain. Gel permeation chromatography (GPC) was performed to determine molecular weight distribution. Transmission electr...

Processing of self-assembled magnetic nanocrystals has vitally scientific and technological interests. In this paper, three different kinds of self-assemblies of cobalt nanocrystals were processed using particles processed by thermal decomposition of cobalt carbonyl in toluene. In case 1, two-dimensional self-assembly of cobalt nanocrystals with an average particle size of 9.2 nm and polydisper...

Previously, we have synthesized a cobaltcontaining diblock copolymer system which exhibited room temperature ferromagnetic properties after phase separation and heat treatment. We have also shown that the morphology and cobalt density in the nanostructured domains both influenced the magnetic properties of these materials due to nanoconfinement which enhanced the dipolar interactions between ot...

Cobalt ferrite (CoFe2O4) nanorods were synthesized by iron chloride (FeCl3.6H2O) and cobalt sulfate hexahydrate (CoSO4.7H2O) as precursor in the presence of ethylene glycol agent and poly vinyl pyrrolidone (PVP) surfactant. The samples were characterized to identify the physical properties. XRD pattern of cobalt ...

Integral heat of solution measurements of barium chloride to 619.81 K, copper oxide in an excess of perrhenic acid to 585 K, and cobalt perrhenate in perrhenic acid to 573 K were measured in a high dilution calorimeter (< or =10(-3) m) at psat, from which the high temperature thermodynamic properties of aqueous barium chloride, copper perrhenate, and cobalt perrhenate were obtained. From the kn...

A novel one-pot laser-assisted approach is reported herein for the synthesis of ordered carbons with embedded cobalt nanoparticles. The process is based on a UV pulsed laser exposure of an ethanolic solution consisting of green carbon precursors, a structure directing agent and a cobalt salt. Very short irradiation times (5 to 30 min) are only required to polymerize and cross-link carbon precur...

In this work, we investigated synthesis, magnetic properties of silica coated metal ferrite, (CoFe2O4)/SiO2 and Manganese doped cobalt ferrite nanoparticles (MnxCo1-xFe2O4 with x= 0.02, 0.04 and 0.06)/SiO2 for possible biomedical application. All the ferrites nanoparticles were prepared by co-precipitation method using FeCl3.6H2O, CoCl2.6H2O and MnCl2.2H2O as precursors, and were silica coated ...