The polydispersity effect of amphiphilic AB diblock copolymers on the self-assembled morphologies in solution has been investigated by the real-space implementation of self-consistent field theory (SCFT) in two dimensions (2D). The polydispersity is artificially obtained by mixing binary diblock copolymers where the hydrophilic or hydrophobic blocks are composed of two different lengths while t...

The classical method of producing cellulose oligomers through hydrolysis microcrystalline (MCC) in phosphoric acid has been re-examined. Hydrolysis products are fractionated by precipitation to yield two types with different average degrees polymerization (DP). number- and weight-averaged molecular weights the lower DP fraction 1339 g/mol 1388 respectively, corresponding a polydispersity index ...

The sound propagation mechanisms inside dense granular matter are challenging the attempts to describe it because of the discrete nature of the material. Phenomena like dissipation, scattering, and dispersion are hard to predict based on the material state and/or properties and vice-versa. We propose here a simulation method using dynamic discrete elements in order to get more insight in this p...

We investigate polydispersity effects on the average structure factor of colloidal suspensions of neutral particles with surface adhesion. A sticky hard sphere model alternative to Baxter’s one is considered. The choice of factorizable stickiness parameters in the potential allows a simple analytic solution, within the “mean spherical approximation”, for any number of components and arbitrary s...

Mixtures of poly(styrene) latices were used to vary the sample polydispersity for an investigation of polydispersity effects on ellipsometric light scattering (ELS) data. A procedure for high-accuracy ELS measurements is presented and the experimental distinction of coherent and incoherent scattering contributions is demonstrated. The ellipsometric parameters tan (phiQ) and delta are solely det...

The melting of a polydisperse hard disk system is investigated by Monte Carlo simulations in the semigrand canonical ensemble. This is done in the context of possible continuous melting by a dislocation unbinding mechanism, as an extension of the 2D hard disk melting problem. We find that while there is pronounced fractionation in polydispersity, the apparent density-polydispersity gap does not...

Magnetorheological fluids (MRF) are smart materials of increasing interest due to their great versatility in mechanical and mechatronic systems. As main rheological features, MRFs must present low viscosity the absence a magnetic field (0.1 - 1.0 Pa.s) high yield stress (50 100 kPa) when magnetized, order optimize magnetorheological effect. Such properties, turn, directly influenced by composit...

poly(styrene-co-butyl acrylate)/clay nanocomposites were synthesized via in situ atom transfer radical polymerization using activators generated by electron transfer in the presence of a montmorillonite ion-exchanged with mixed surfactants of dodecyl trimethyl ammonium bromide and vinyl trimethyl ammonium chloride. the living nature of polymerization is confrmed by occurrence of narrow molecula...

We present a generalized connectedness percolation theory reduced to a compact form for a large class of anisotropic particle mixtures with variable degrees of connectivity. Even though allowing for an infinite number of components, we derive a compact yet exact expression for the mean cluster size of connected particles. We apply our theory to rodlike particles taken as a model for carbon nano...