Research into the photochcmistry of biopolymcrs has increased in scope and scale to such an extent in recent years that it has become necessary to limit this review to a consideration of photochemical approaches to the structure of polynucleotides. Treatment proceeds from the constituent monomers to the polymer to emphasize the changes in photophysical and photochemical properties of the monome...

Seoul is one of the most severe smoggy cities in the world. During summer afternoons, the fine particles formed by photochemical reactions could contribute visibility reduction. The formation and growth of secondary ambient aerosols might be affected by primary air pollutants and by meteorological factors. In this work, the photochemical reaction of Seoul ambient air was investigated in indoor ...

Top-down fabricated nanoantenna architectures of both metallic and dielectric materials demonstrated powerful functionalities for Raman fluorescence enhancement with relevance to single molecule sensing, while inducing directionality chromophore emission implications photon sources. Herein, we synthesize the smallest bowtie by selective tip-to-tip fusion two tetrahedral colloidal quantum dots (...

A new molybdenum porphycene complex, which is a new complex having oxo and chloro groups at the axial positions, was successfully synthesized. This chloro(oxo)molybdenum(v) complex, [Mo(V)(OEPc)(O)Cl] (1) has strong absorption bands in the visible region attributed to the properties of the porphycene and is very attractive from a photochemical viewpoint. This complex was readily reduced from Mo...

A quantum yield of •i•e = 2.3 x 10 '4 (+_ 4 X 10 -•) was determined for the photochemical degradation of 4nitrophenol over the wavelength range of 300 to 370 nm in ice pellets (pH 5.6). Five reaction products were identified: hydroquinone, benzoquinone, 4-nitrosophenol, nitrate, nitrite, and the likely formation of organic polymers. The similarities of these results to the observations from 4-n...