Determination of total nitrogen in aqueous samples after potassium persulfate digestion compared favorably in both precision and nitrogen recovery with determinations obtained using Kjeldahl digestion. The determination of total nitrogen (TN = inorganic and organic fixed nitrogen) has largely depended either on acid Kjeldahl digestion ( cf. Strickland and Parsons 1972) or on photo-oxidation (Ar...

Mesoscopic anatase nanocrystalline TiO2 (nc-TiO2) electrodes play effective and efficient catalytic roles in photoelectrochemical (PEC) H2O oxidation under short circuit energy gap excitation conditions. Interfacial molecular orbital structures of (H2O)3 &OH(TiO2)9H as a stationary model under neutral conditions and the radical-cation model of [(H2O)3&OH(TiO2)9H]+ as a working nc-TiO2 m...

It has recently been suggested that the active site histidine residue in papain and stem-bromelain have pK, values of 6.7 and 6.4 respectively and since these enzymes are essentially pH-independent for substrate hydrolysis at these pH values, histidine is not directly involved in their catalytic mechanism [l-3] This conclusion is based on photo-oxidation experiments during which the active site...

Our previous study revealed that aqueous extract of grape pomace obtained from a winemaking process could exert bactericidal action upon photo-irradiation via reactive oxygen species (ROS) formation. In the present study, we focused on chemical composition and prooxidative profile of the extract. Liquid chromatography-electrospray ionization-mass spectrometry (LC-ESI-MS) analysis showed that po...

background textile dyes are the largest organic compounds associated with some problems for the environment. advanced oxidation process is the most effective method for dye removal from wastewater. objectives the aim of this study was to investigate the efficiency of the photo fenton process for decolorization of direct red 81 (dr 81) dye, and to determine the optimal process conditions. method...

Oxygenate photo-reforming: A process of harnessing the redox ability a photocatalyst to simultaneously drive reduction H + into 2 and oxidation organics.

Secondary organic aerosol (SOA) is transformed after its initial formation, but this chemical aging of SOA is poorly understood. Experiments were conducted in the Carnegie Mellon environmental chamber to form secondary organic aerosol (SOA) from the photo-oxidation of toluene and other small aromatic volatile organic compounds (VOCs) in the presence of NOx under different oxidizing conditions. ...

Key words (±)-talatisamine - Diels–Alder reaction [2+2] photo-cycloaddition Lemieux–Johnson oxidation retro-aldol–aldol Wagner–Meerwein rearrangement aza-Prins