Fluorescence analysis is a simple and highly sensitive method for detection of small amounts biologically active substances. In this study, complexation terbium(III) chelates with 1,10-phenanthroline ascorbic acid (AA) luminescent properties complexes were investigated. The influence pH solubilization by micellar solutions nonionic, cationic, anionic surfactants on fluorescence was studied. que...

This paper made an analysis about advantage and disadvantage of Guangxi non-ferrous metal industry. Based on the RBF neural network model, the paper then gave an evaluation of technological innovation ability about non-ferrous metal industry in Guangxi. And then, the paper proposed some suggestions how to better develop non-ferrous metal industry in Guangxi.

Many bituminous coal mine effluents contain, along with other ions, high concentrations of ferrous iron. This is brought into solution by sulfuric acid produced by the oxidation of sulfuritic material, possibly iron sulfides in part, occurring with bituminous coal (Leathen et al., 1952). The ferrous iron is oxidized by bacteria to the ferric state at a more rapid rate than can be accounted for ...

In this work, we report the electrochemical response of a family Co(II) complexes, [CoII(L)3]2+ and [CoII(L’)2]2+ (L = 2,2’-bipyridine, 1,10-phenanthroline, 3,4,7,8-tetramethyl-1,10-phenanthroline, 5,6-dimethyl-1,10-phenanthroline, 4,7-diphenyl-1,10-phenanthroline; L’ terpyridine 4-chloro-terpyridine), in presence absence CO2 order to understand role redox potential molecular structure on catal...

Dye-sensitized solar cells transform light into electricity. One commonly used dye is a ruthenium complex. However, the use of has been shown to have several disadvantages. In this study, via singular spectrum analysis using HypSpec software, we determined formation constants and calculated individual electronic spectra species iron(III) with ligands (1,2-diaminoethane, 1,3-diaminopropane, 1,4-...

Objective(s): Iron is an essential element for living organisms. Iron overload can have detrimental effects on health. This study pertains to the protective role of berberine against ferrous sulfate-induced hepatic and renal functional disorders and histological damages in rats.Materials and Methods: The rats were divided into four groups (n=7): Sham, Ber (10 mg/kg/day for 14 days, by gavage), ...

The asymmetric unit of the title compound, C(12)H(8)N(2)·0.5C(2)H(4)N(2)S(2), contains one 1,10-phenanthroline mol-ecule and a half-mol-ecule of dithio-oxamide, which lies across a crystallographic inversion center. The 1,10-phenanthroline unit is not strictly planar, with dihedral angles between the central benzene ring and the pyridine rings of 1.42 (10) and 1.40 (10)°. In the crystal structu...

The oxidation of ferrous iron by Acidithiobacillus ferrooxidans in the pH range 2.5–7.0 was characterized. In order to measure the rate of bacterial oxidation of ferrous iron with A. ferrooxidans in this high pH range, a novel experimental methodology was developed. The results showed that the inhibition of ferrous iron oxidation activity by A. ferrooxidans observed at pH values above 3.0 is pa...

The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal-planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenyl-phosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenyl-phosphine ligand almost lie in one plane (maximum deviation = 0....