In the present study, theoretical chemical reactivates Photo isomerization in Cis-Retinal as a Natural Photo switch in Vision. DFT hybrid functional, B3LYP and, post-HF method, were the theoretical methods applied utilizing G09 software. 6-31G+ (d,p) basis set employed for structural optimizations, and single point computations performed using B3LYP/6-31G+(d,p). The isomers cis molecule retinal...

The enzymatic potential of the cultured plant cells can be employed for bioconversion purposes. Plant enzymes are able to catalyze regio- and stereo-specific reactions, and therefore can be applied for the production of desired substances. The biotransformation of foreign substrates with suspension cells of Peganum harmala was tested with (±) phenylethyl propionate. The callus cultures of Pegan...

The reactions of a variety of bis(tricyclohexylphosphine)nickel species with C 0 2 have been studied. The product of the reaction is solvent dependent: in toluene the known complex [NiL2(/7 -C02)]-toluene (L = PCy3) is formed while in ether or pentane a binuclear complex [(NiL2)2(?;-C02)] results through the intermediacy of the solvent free species [NiL2(//-C02)] the structure of which has been...

The effect of dietary lipids on the toxicity of methylmercury (MeHg) was investigated in experimental MeHg poisoning of rats. Three groups of weanling rats, with 8 to 12 animals in each group, were fed on vitamin E-deficient diet containing 10% beef tallow, cod liver oil or corn oil respectively for 5 weeks and the amount of plasma TBA (Thiobarbituric acid) -reactants, expired ethane and pentan...

Anti aldol reactions of an l-erythrulose derivative with several α-chiral aldehydes mediated by dicyclohexylboron chloride are examined. Good yields and stereoselectivities are observed. The results are best explained when the reactions are assumed to occur via boat-like transition states with minimization of 1,3-allylic strain and avoidance of syn pentane interactions.

This study aimed to establish primary reactions and identify gaseous products during fast pyrolysis of low-density polyethylene (LDPE), polypropylene (PP) polystyrene (PS). Fast was performed by using Py-GC/MS/FID at 574 ± 22 °C for 5 s. Gaseous fractions formed LDPE, PP PS were 14 1 wt%, 31 3 wt% 103 12 respectively. The main compounds from LDPE butane, 1-pentane 1-hexene. gave propene, pentan...

Two possible isomers of some 1,3-diaryl-H-benzo[f]chromene have been studied using density functional theory. Structures of E1 and E2 isomers were optimized at the B3LYP and MP2 levels with different basis sets. The total electronic energies show that E2 isomer is about 3-5 kcal/mol more stable than E1 isomer and this energy difference is attributed to the planarity of heterocyclic ring and mor...