UNIVERSITY OF TURKU Depaartment of Chemistry/Faculty of Mathematics and Natural Sciences Golubev, Oleg: Recognition of nucleic acids by metal ion complexes Doctoral thesis, 144 p. Laboratory of Organic Chemistry and Chemical Biology March 2016 Metal-ion-mediated base-pairing of nucleic acids has attracted considerable attention during the past decade, since it offers means to expand the genetic...

in this research work, a novel parallel manipulator with high positioning and orienting rate is introduced. this mechanism has two rotational and one translational degree of freedom. kinematics and jacobian analysis are investigated. moreover, workspace analysis and optimization has been performed by using genetic algorithm toolbox in matlab software. because of decreasing moving elements, it i...

introduction multiple dentigerous cysts are rare and mostly associated with syndromes. case presentation the present case report is unique, as the dentigerous cysts enclosed the lateral incisor, canine, first and second premolars of the mandible and were accompanied by a complex odontoma, instead of first mandibular molar. conclusions multiple unilateral nosyndromic dentigerous cysts with compl...

Supported Pd/CeO2 catalytic systems have been widely investigated in the low-temperature oxidation of CO (LTO CO) due to unique oxygen storage capacity and redox properties ceria support, which highly influence structural, chemical electronic state Pd species. Herein, operando near-ambient pressure XPS (NAP-XPS) technique has allowed study a conventional catalyst surface during reaction under e...

abstractinteraction of ni complex(salen= n, n´-ethylene bis(salicylideneimine)) with hen egg-white lysozyme (hewl) was studied by absorption spectroscopy, competitive binding study and thermal denaturation study. the protein binding affinity of ni complex was found to be (3.0×103m−1). the binding plot obtained from the absorption titration data gives a binding constant of 2.4 (± 0.3)×103 m-1. i...