The new conjugated organometallic polymer (-spacer-C[triple bond]C-Pt(PBu3)2-C[triple bond]C-)n (3; spacer = para-bis(diphenyl(tetramethyl)quinone diimine) and the cyclic mononuclear model complex, spacer'-C[triple bond]C-Pt(PEt3)2-C[triple bond]C x CuCl (4; spacer' = ortho-diphenyl-2,3,5,6-tetramethyl-1,4-benzoquinone diimine) were synthesized from the 1:1 condensation of the corresponding die...

The title compound, C(17)H(26)O, is a di-ortho-alkyl substituted phenyl ethanone that exhibits a significant twisting of the ketone fragment relative to the aromatic ring [O-C-C-C torsion angle = 89.32 (17)°] due to steric pressure from the ortho-isopropyl groups. One ortho- and the para-isopropyl group exhibit orientational disorder with a refined site occupancy factor of 0.562 (3):0.438 (3).

We discuss the production of ortho-projection graphs from alternating knot diagrams, and introduce a more general construction of such graphs from “splittings” of closed, non-orientable surfaces. As our main result, we prove that this new topological construction generates all ortho-projection graphs. We present a minimal example of an ortho-projection graph that does not arise from a knot diag...

A Chevalley type integral basis for the ortho-symplectic Lie superalgebra is constructed. The simple modules of the ortho-symplectic supergroup over an algebraically closed field of prime characteristic not equal to 2 are classified, where a key combinatorial ingredient comes from the Mullineux conjecture on modular representations of the symmetric group. A Steinberg type tensor product theorem...

The synthesis of tetra-ortho-substituted biaryl naphthalenes, including examples bearing multiple ortho-isopropyl groups, has been developed via a catalytic rearrangement process.

4-Iodo-pyrano[4,3-b]quinolines and ortho-alkynyl esters were synthesized selectively from ortho-alkynyl aldehydes by an iodine-catalyzed and solvent controlled reaction.

The first four-dimensional (4D) adiabatic potential energy surface (PES) for the interaction of NO+ cation with H2 molecule has been accurately determined using CCSD(T)-F12a method cc-pVTZ-F12 basis set augmented mid-bond functions. A detailed characterization PES and lowest bound states H2–NO+ complex have provided. exhibits a single global minimum well depth −824.63 cm−1 corresponding to off-...