Hybridization-related modifications of the first metal layer of a metal-organic interface are difficult to access experimentally and have been largely neglected so far. Here, we study the influence of specific chemical bonds (as formed by the organic molecules CuPc and PTCDA) on a Pb-Ag surface alloy. We find that delocalized van der Waals or weak chemical π-type bonds are not strong enough to ...

recently, using the source of organic fertilizers and biofertilizers in sustainable crop production is growing. in order to evaluate the effect of organic compounds, biofertilizers and chemical fertilizer on morphological properties, yield and yield components of forage sorghum (sorghum bicolor) a field experiment was conducted in the research farm, college of agriculture, ferdowsi university o...

This work proposes OCLAS (Organic Chemistry Language Ambiguity Solver), an automatic system to analyze syntactically and semantically Organic Chemistry compound names and to generate the pictures of their chemical structures. If both parses detect that the input name corresponds to a theoretically possible organic chemical compound, the system generates its molecular structure picture, whether ...

Organic phosphorus is an important component of soil biogeochemical cycles, but must be extracted from soil prior to analysis. Here we critically review the extraction of soil organic phosphorus, including procedures for quantification, speciation, and assessment of biological availability. Quantitative extraction conventionally requires strong acids and bases, which inevitably alter chemical s...

A new and versatile, crown ether appended, chiral supergelator has been designed and synthesized based on the bis-urea motif. The introduction of a stereogenic center improved its gelation ability significantly relative to its achiral analogue. This low-molecular-weight gelator forms supramolecular gels in a variety of organic solvents. It is sensitive to multiple chemical stimuli and the sol-g...

We have systematically studied interface structure formed by vapor-phase deposition of typical transition metal oxide MoO3 on organic semiconductors. Eight organic hole transport materials have been used in this study. Ultraviolet photoelectron spectroscopy and X-ray photoelectron spectroscopy are used to measure the evolution of the physical, chemical and electronic structure of the interfaces...

Continuous use of chemical fertilizers has deteriorated the soil health and made the use of organic matter essential to restore the soil health and productivity. The availability of organic matter is again a problem because of the increase in area under crop cultivation. Thus recycling of the available organic wastes from the existing gardens especially in perennial crops gets more importance. ...

A detailed understanding of the sources, transformations and fates of organic species in the environment is crucial because of the central roles that they play in human health, biogeochemical cycles and the Earth's climate. However, such an understanding is hindered by the immense chemical complexity of environmental mixtures of organics; for example, atmospheric organic aerosol consists of at ...

Changes in soil physical and chemical properties were evaluated in several on-farm studies located in rainfed, hardsetting red Al®sols (Ferric Luvisols) and in irrigated, self-mulching Vertisols (Chromic Vertisols) of eastern Australia. The objective of the studies was to evaluate changes in soil physical and chemical properties with time under commercial farming situations where changes had be...