نتایج جستجو برای: non ideal thermodynamic behavior

تعداد نتایج: 1972302  

Journal: :Physical chemistry chemical physics : PCCP 2015
Mirco Zerbetto Diego Frezzato

We illustrate how the Jarzynski equality (JE), which is the progenitor of non-equilibrium methods aimed at constructing free energy landscapes for molecular-sized fluctuating systems subjected to steered transformations, can be applied to derive equations of state for bulk systems. The key-step consists of physically framing the computational strategy of "total energy morphing", recently presen...

Journal: :Journal of Physical and Chemical Reference Data 1976

Let R be a non-domain commutative ring with identity and A(R) be theset of non-zero ideals with non-zero annihilators. We call an ideal I of R, anannihilating-ideal if there exists a non-zero ideal J of R such that IJ = (0).The annihilating-ideal graph of R is defined as the graph AG(R) with the vertexset A(R) and two distinct vertices I and J are adjacent if and only if IJ =(0). In this paper,...

2013
Sauro Pierucci Jiří J. Klemeš Antonio C. D. Freitas Reginaldo Guirardello

Supercritical water gasification (SCWG) is an alternative thermochemical technology for the conversion of wet biomass in a high heat value product gases, such as syngas and hydrogen. Algal biomass has been suggested as one promising option to produce biomass for use as fuels and chemical feedstocks with high area-specific yields. In this study, the thermodynamic analysis of SCWG of microalgae b...

2008
Peter Borrmann Jens Harting Oliver Mülken Eberhard R. Hilf

We derive an exact recursion formula for the calculation of thermodynamic functions of finite systems obeying Bose-Einstein statistics. The formula is applicable for canonical systems where the particles can be treated as noninteracting in some approximation, e.g. like Bose-Einstein condensates in magnetic traps. The numerical effort of our computation scheme grows only linear with the number o...

2016
S. N. Kempkes A. Quelle C. Morais Smith

Topological insulators (superconductors) are materials that host symmetry-protected metallic edge states in an insulating (superconducting) bulk. Although they are well understood, a thermodynamic description of these materials remained elusive, firstly because the edges yield a non-extensive contribution to the thermodynamic potential, and secondly because topological field theories involve no...

2014
Christian Ley Julien Christmann Ahmad Ibrahim Luciano H Di Stefano Xavier Allonas

The combination of a dye which absorbs the photon, an electron acceptor and an electron donor leading to energy conversion through electron transfer, was the basis of the so called three-component systems. In this paper, an experimental work combining Rose bengal dye with a triazine derivative as electron acceptor and ethyl 4-(dimethylamino)benzoate as electron donor, will underline the benefit...

Journal: :Physical review letters 2015
Eric C Andrade Anuradha Jagannathan Eduardo Miranda Matthias Vojta Vladimir Dobrosavljević

Motivated by the intrinsic non-Fermi-liquid behavior observed in the heavy-fermion quasicrystal Au51Al34Yb15, we study the low-temperature behavior of dilute magnetic impurities placed in metallic quasicrystals. We find that a large fraction of the magnetic moments are not quenched down to very low temperatures T, leading to a power-law distribution of Kondo temperatures P(T(K))∼T(K)(α-1), with...

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