Nickel serves as a cofactor for various microbial enzymes including superoxide dismutase (SOD) found in Streptomyces spp. In Streptomyces coelicolor, nickel represses and induces production of Fe-containing and Ni-containing SODs, respectively, primarily at the transcriptional level. We identified the nickel-responsive regulator (Nur), a Fur (ferric-uptake regulator) homologue, which binds to t...

Reactions of nine-atom deltahedral clusters of germanium with Ni(COD)2 and/or Ni(PPh3)2(CO)2 in ethylenediamine yielded the Ni-centered heteroatomic 10-atom clusters [Ni@(Ge9Ni-CO)]2- and [Ni@(Ge9Ni-en)]3-, as well as the empty 10-atom heteroatomic cluster [Ge9Ni-CO]3-. A ligand exchange reaction between [Ni@(Ge9Ni-CO)]2- and potassium phenylacetylide produced the organically functionalized spe...

Nitrogenase is an essential metalloenzyme that catalyzes the biological conversion of dinitrogen (N(2)) to ammonia (NH(3)). The vanadium (V)-nitrogenase is very similar to the "conventional" molybdenum (Mo)-nitrogenase, yet it holds unique properties of its own that may provide useful insights into the general mechanism of nitrogenase catalysis. So far, characterization of the vanadium iron (VF...

A facile technique was demonstrated for the controlled assembly and alignment of multi-segment nanowires using bioengineered polypeptides. An elastin-like-polypeptide (ELP)-based biopolymer consisting of a hexahistine cluster at each end (His(6)-ELP-His(6)) was generated and purified by taking advantage of the reversible phase transition property of ELP. The affinity between the His(6) domain o...

The presence of heavy metals in plants from oil sand deposits may reflect mineralization resulting petroleum biodegradation. Petroleum composition and metal analyses were performed using thermal desorption gas chromatography atomic absorption spectrophotometry on plant root samples the same localities Dahomey Basin. results showed mainly heavy-end hydrocarbon components, humps unresolved comple...

Abstract Adsorption is an important phenomenon widely used for the removal of contaminants. Several drinking water contaminants such as arsenic and fluoride, vanadium chromium, nickel, cadmium cobalt are found to coexist in nature multi-component mixtures water. Hence, modeling adsorption isotherms designing treatment systems has gained importance recently. However, review studies competitive l...