Shape and size of the synthesized NiO nano-sheets were retained during transformation of sheet-like b-Ni(OH)2 to NiO at elevated temperatures via nano-sized zirconia coating on the surface of b-Ni(OH)2. The average grain size was 6.42 nm after 600 C treatment and slightly increased to 10 nm after 1000 C treatment, showing effective sintering retardation between NiO nano-sheets. The excellent th...

In this work, a new mechanism is proposed for the redox of hypophosphorous acid catalyzed by a nickel cluster through a combined study of density functional theory (DFT) calculations and electrochemical impedance spectroscopy (EIS) measurements. The DFT results indicate that the concentration of OH is a crucial species to control the oxidation and reduction of hypophosphorous acid. The oxidatio...

The spectral imagings were performed in order to examine the lateral resolution of the EDX analysis which is attached in an ultra low acceleration voltage SEM. The spectral imagings were performed for the cross section of the Ni coating on Al, which was cut using microtome, and the cross section of GaAs/AlAs super-lattice, which was cleavaged, using a ultra-low-acceleration-voltage SEM and EDX....

The cold metal transfer (CMT) welding-brazing process was chosen to join Al alloy and Ni-coated steel using AlSi12 as the filler wire. macrostructure microstructure of joints were tested by an optical microscope (OM), scanning electron (SEM), energy dispersive spectrometry (EDS), X-ray diffraction (XRD). tensile properties corrosion also tested. results showed that Ni coating could improve wett...

In an attempt to control the film composition, factors affecting the composition of Ni-Fe alloy deposits and their crystal structure have been analyzed as a function of bath composition, cathode current density, bath pH, temperature and an addition of citric acid. antimony electrode revealed that the deposition potential of Fe coincides with the potential where the abrupt increase of pH was obs...

The present study outlines the use of Taguchi parameter design to minimize the wear performance of electroless Ni-B coating by optimizing the tribological testing parameters. The tests are carried out in a multitribotester and the three parameters viz. load (L), speed (S) and time (T) are considered with three levels each. An L27 array is used to accommodate the three factors as well as their i...

in the present study, ni-p-cnt composite coating was successfully fabricated via electroless plating. scanning electron microscopy (sem) was used to characterize the coatings. the effect of cnts concentration in the bath on its content in the composite coatings was studied. furthermore, the corrosion behaviour of the coatings with different contents of cnts was evaluated using tafel polarizatio...

Three-dimensionally (3D) nanoarchitectured palladium/nickel (Pd/Ni) catalysts, which were prepared by atomic layer deposition (ALD) on high-aspect-ratio nanoporous alumina templates are investigated with regard to the electrooxidation of formic acid in an acidic medium (0.5 M H2SO4). Both deposition processes, Ni and Pd, with various mass content ratios have been continuously monitored by using...

In this work the effects of WC concentration on abrasive wear behavior by thermally sprayed WC coating was evaluated using three body abrasive wear tester. A different combination of WC and NI coatings were deposited on steel substrates by flame spraying using powder with different WC concentrations (0 %, 12.5 %, 25 %, and 50 %). Flame torch was used for heating and coating of process. Microstr...