Decorating of Transition metals (TMs) on the "AlMg" nanoalloy has been studied basis Langmuir adsorption applying "ONIOM" model with three levels «high, medium and low» by using "LANL2DZ /6-31+G(d,p)/EPR-III", "semi-empirical" "MM2" functions. The fluctuation "NQR" estimated inhibiting role pyridine alkylpyridines containing 2-picoline (2Pic), 3-picoline (3Pic) ,4-picoline (4Pic), 2,4-lutidine ...