Potentiostatic, galvanostatic and cyclic potentiodynamic depositions of polyaniline were studied by cyclic voltammetry and in-situ Raman spectroscopy. Multivariate analysis of the spectroelectrochemical data including evolving factor analysis, multivariate curve resolution and 2Dcorrelation spectroscopy was applied to resolve overlapped bands in Raman spectra and to assign them reliably. Oxidiz...