We study the selective catalytic oxidation of ethanol with air as a sustainable alternative route to acetaldehyde. The reaction is catalysed by molybdenum oxide supported on titania, in a flow reactor under ambient pressure. High selectivity to acetaldehyde (70%-89%, depending on the Mo loading) is obtained at 150 °C. Subsequently, we investigate the structure/performance relationship for vario...

Although most of the rare earth metals were discovered in Sweden, the industrialisation started in the Austrian Empire. This was due to the fact that the Swedish chemist Jons Fridrik Bahr (1815–1875) from Uppsala went to Heidelberg in Germany in 1855 to analyse some rare earth minerals by the spectroscope discovered recently by chemistry professor Robert Bunsen (1811– 1899) and his colleague ph...

Modern trends in iron metallurgy. Global carbon emissions from iron production. New solution for iron and steelmaking in a way reduce the CO2 emission to the level, where this might be needed in the post Kyoto period. New blast furnace technology, which operate with very low CO2 emissions based on drastically reduced consumption of carbon containing input materials. Injection of reducing gases ...

A new generation of alloys, which rely on a combination of various strengthening mechanisms, has been developed for application in molten salt nuclear reactors. In the current study, a battery of dispersion and precipitation-strengthened (DPS) NiMo-based alloys containing varying amounts of SiC (0.5-2.5 wt %) were prepared from Ni-Mo-SiC powder mixture via a mechanical alloying (MA) route follo...

Coating is one of the innovative approaches used to improve the wear resistance and load-carrying capacity of surfaces in rolling-sliding contact, such as gears and rolling element bearings. In this study, the tribological performance of standard gear material (EN 16MnCr5) and two kinds of powder metallurgy (PM) gear material (Distaloy AQ + 0.2% C and Astaloy 85Mo +0.2% C) with and without trib...

Future improvements to jet engine performance will require materials which are lower in density and can withstand higher temperatures; thus increasing the thrust-to-weight ratio and the engine efficiency. The intermetallic compound IB-NiA1 is a prime candidate for this new high temperature material. This intermetallic offers a low density, a high melting temperatme, and excellent oxidation resi...

In this study, molybdenum-copper/alumina nano composite was synthesized with mechano-chemical method using high energy planetary ball milling. The molybdenum oxide, copper oxide and aluminum powder were used as starting materials and reaction appeared to occur through a rapid combustion reaction process. The evaluation of powder particles after different milling times was studied by X-ray diffr...

Aluminium alloy composites have been extensively investigated for use in tribo-contact applications, however little detailed literature exists on the sub-surface microstructural evolution as a result of lubricated sliding wear. In this study two un-reinforced alloys (2124 & 5056) and identical alloy composites, reinforced with 15vol.% MoSi2 intermetallic particles were produced by a powder meta...

   Nickel-molybdenum oxidebimetallic nanoparticles were synthesized in ethylene glycol using the microwave irradiation technique. According to the results, successive reduction of nickel and molybdenum ions, followed by thermal treatment of obtained nanoparticles led to formation of core-shell structured nickel-molybdenum oxide nanoparticles. According to the results, the thickness of the s...

The importance of metallurgy for social and economic development is indisputable. Although copper (Cu) was essential for the wealth of pre- and post-colonial societies in the Andes, the onset of extensive Cu metallurgy in South America is still debated. Comprehensive archaeological findings point to first sophisticated Cu metallurgy during the Moche culture ~200-800 AD, whereas peat-bog records...