Introduction – Shrinkage during polymerization of resin-based composite materials may lead to gap formation and hamper the marginal adaptation of the restorations. To reduce the problem of polymerization shrinkage, a new composite material (FiltekTM Silorane, 3M-ESPE, Germany), with a reduced shrinkage, has been marketed. Objective – To investigate whether reduced polymerization shrinkage impro...

Two types of ceramic-polymer composite thick films were deposited on Cu substrates by an aerosol deposition process, and their properties were investigated to fabricate optimized ceramic-based polymer composite thick films for application onto integrated substrates with the advantage of plasticity. When polymers with different mechanical properties, such as polyimide (PI) and poly(methyl methac...

In this work, we report the successful fabrication of CO2-philic polymer composite membranes using a polyacrylonitrile-r-poly(ethylene glycol) methyl ether methacrylate (PAN-r-PEGMA) copolymer. The series of PAN-r-PEGMA copolymers with various amounts of PEG content was synthesized by free radical polymerization in presence of AIBN initiator and the obtained copolymers were used for the fabrica...

The intimate marginal adaptation of composite resins is considered to be the most important requisite, and this is strongly influenced by polymerization shrinkage, thermal expansion or mechanical properties of the resins. The highly loaded composite resins, developed recently have yielded good results on thermal expansion and mechanical properties. Consequently, little attention has been paid t...

The aim of this study was to observe the influence of two light polymerization units (LED or halogen light) on the degree of conversion (DC) of three dental composites with lighter shades and a different photoinitiator system. The top (T) and bottom (B) surfaces of 60 discs of composite resin (Filtek™ Supreme, Filtek™ Z250, Tetric™ Ceram Bleach) cured either by LED or by halogen lamp (HL) were ...

OBJECTIVES A multitude of acrylic monomers is used in dentistry. Formaldehyde is a ubiquitous chemical agent, which is an ingredient of some dental materials and may be released from methacrylate-based composites. The purpose of the study is to evaluate the incidence and the risk of cross-sensitization to some methacrylic monomers (methylmethacrylate - MMA, triethyleneglycol dimethacrylate - TE...

OBJECTIVES This study evaluated the influence of the cavity configuration factor ("C-Factor") and light activation technique on polymerization contraction forces of a Bis-GMA-based composite resin (Charisma, Heraeus Kulzer). MATERIAL AND METHODS Three different pairs of steel moving bases were connected to a universal testing machine (emic DL 500): groups A and B - 2x2 mm (CF=0.33), groups C ...

We studied the second-order NLO properties in solution of various Ir(III) acetylacetonate complexes bearing a substituted cyclometallated 4-styryl-2-phenylpyridine (ppy-4-styryl-R, with R = NEt2, OMe, H, NO2) with the EFISH technique. The dipole moments were evaluated by Density Functional Theory (DFT) calculations. We have also investigated the Second Harmonic Generation (SHG) of composite fil...

OBJECTIVES The aim of this study was to investigate the effect of layering methods, flowable composite liner and use of low shrinkage silorane-based composite on the polymerization shrinkage stress of light cured composites. METHODS Aluminum blocks were used to prepare MOD cavities and divided into four groups. A universal hybrid methacrylate-based composite (Z250), a flowable composite (Z350...