نتایج جستجو برای: mercury complexes
تعداد نتایج: 178189 فیلتر نتایج به سال:
Stability constants from molecular weigth measurements for the complexes R2Hgbpy (bpy = 2,2'-bipyridyl) in carbon tetrachloride and benzene at 25 °C decrease in the order R = CaF5 > > p-HC6F4 = p-MeOC6F4 2':: o-HC5F4, and for R2HgOPPha, in the order R = o-HC6F4 > C5F5 > p-HC5F4 = p-MeOC5F4 with higher values in the former solvent. The unexpectedly greater stability of (o-HC5F4)2HgOPPha than (C5...
abstract amino acids are building blocks of proteins, and play a vital role in living beings existence and their functionality. the interaction of these compounds with metal ions is of great importance to biochemists, and chemists, because their functions can be utilized as a model in understanding enzymes mechanism for transport of metal ions to tissues. among twenty essential amino acids w...
Detection and separation of metals from fresh water and industrial effluents has become a pre-requisite for any nation in the world. In and around the city of Hyderabad (Sindh), Pakistan, the home as well as cottage industry which consumes chemicals containing the copper, mercury, cadmium and lead are freely dumped into local ravines and canals unchecked for many years. The process is polluting...
Recently, 6-(2-naphthyl)-2, 3-dihydro-as-triazine-3-thione (NDTT) was synthesized in laboratory and used successfully for the spectrophotometric determination of nanogram levels of Cu2+ in aqueous solution. This reagent forms a specific red complex with Cu2+ ions after the extraction by chloroform at alkaline pH. The absorption of the complex in the UV region (313 nm) is about 8 times as strong...
Recently, 6-(2-naphthyl)-2, 3-dihydro-as-triazine-3-thione (NDTT) was synthesized in laboratory and used successfully for the spectrophotometric determination of nanogram levels of Cu2+ in aqueous solution. This reagent forms a specific red complex with Cu2+ ions after the extraction by chloroform at alkaline pH. The absorption of the complex in the UV region (313 nm) is about 8 times as strong...
abstract the influence of cation?? and anion?? interactions on the strength and nature of n…h hydrogen bond has been investigated by quantum chemical calculations in s-triazine…3hf complex. ab initio calculations were performed at mp2/6-311++g(d,p) level of theory. the natural bond orbital (nbo) analysis and the bader’s quantum theory of atoms in molecules (aim) were also used to elucidate t...
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