Studies of clusters in condensed phase at atmospheric pressure are very important for understanding the properties and structures of liquids. Liquid-ionization (LPI) mass spectrometry is useful to study hydrogen-bonded clusters at the liquid surface and in a gas phase. An improved ion source connected to a tandem mass spectrometer provides detailed information about clusters. Mass spectra of pu...

A high-loading Ga-exchanged MFI zeolite was developed for efficient ethane dehydrogenation. Its high catalytic performance is ascribed to both the low amount of Brønsted acid sites and major formation [GaH 2 ] + ions among isolated Ga hydrides.

After initial commissioning of the charge state breeder for radioactive ions at the TRIUMF/ISAC facility further tests on the performance of the system have been done., One of the major problems found was the high background of stable ions from the ECR source. The main source of those is the residual gas and sputtered material from the plasma chamber wall and from the surrounding electrodes. Al...

the solvent extraction of rare earth metal ions from nitrate solutions by 5.11.17.23-tetra-tert-butyl-25,27-bis(diethylcarbamoylmethoxy)-26,28-dihydroxycalix[4]arene (l) in 1,2-dichloroethane has been investigated. the alalysis of the extraction equilibrium obtained from a mixture of la3+, eu3+, er3+ and y3+ revealed that the extracted species have a 1:1 metal/ligand ratio. the intra-group sepa...

co-precipitation procedure was applied in order to obtain different kinds of magnetic nanoadsobents for the removal of pb(ii) and cu(ii) toxic metal ions from wastewater samples. prepared nanoadsorbents were characterized by fourier transform infrared spectroscopy (ft-ir), x-ray diffractometer (xrd), scanning electron microscopy (sem) and thermogravimetric analysis (tga). the average sizes of t...

salinity is one of major stresses which can severely limit plant production, especially in the arid and semi-arid regions. the present study was carried out to evaluate the impact of salinity stress on some physio-biochemical parameters in nitre bush plants (nitraria schoberi). thus, an experiment was carried out under natural conditions and salinity stress was induced by a combination of diffe...

This study focuses on lead detoxification using roots, stems, leaves and whole plants of Plantago major L. and Phaseolus vulgaris L. (decoration kidney bean) as a ball hanging hydroponically in deionized water supplemented with concentrations of lead ion under different duration times and temperatures regimes. Roots of studied plants showed that the highest removal of lead than other parts, whi...

X-ray powder diffraction and chemical analyses show that mammalian dental enamel apatite is an impure form of hydroxylapatite, Ca10(PO4)6(OH)2 (structure described in Elliott 1994). The major difference of enamel apatite from hydroxylapatite is in the presence of about 3 wt% CO3. Details of the crystallographic structures of carbonate-containing apatites (including minerals) are important becau...

The Clinch and Powell Rivers (Virginia, USA) support diverse mussel assemblages. Extensive coal mining occurs in both watersheds. In large reaches of both rivers, major ion concentrations are elevated and mussels have been extirpated or are declining. We conducted a laboratory study to assess major ion effects on growth and survival of juvenile Villosa iris. Mussels were exposed to pond water a...

oxime extractants 3-tert-butyl-2-hydroxy-5-methyl benzaldehyde oxime (hl1) and 3-tert-butyl-2-hydroxy-5-methoxy benzaldehyde oxime (hl2) were synthesized and characterized by conventional spectroscopic methods. suitable lipophilic nature of the prepared extractants allowed examining the ability of these molecules for extraction-separation of copper from its mixture with normally associated meta...