Special binding sites in graphene are beneficial for near-surface interaction. These sites, which supplied by single-atom catalysts, change the electronic characteristics of and its derivatives, greatly expanding potential use as gas sensors. Iron–nitrogen–carbon is reflected one most effective substitutes platinum oxygen reduction reactions. The selection carbon-enclosed FeN4 moieties, serve c...

New electrochemical technique with a Pt-Ag twin electrode is proposed for the determining the contents of iron sulfides (FeS and FeS(2)) in a suspension. After electrolytic oxidation with a Pt electrode, Fe(2+) was measured by linear sweep voltammetry. From relations of the charge amount from the baseline to the peak in the voltammogram of Fe(2+) with the content of FeS or FeS(2), linear calibr...

The reaction of [Fe(2)(mu-OH)(2)(6-Me(3)-TPA)(2)](2+) (1) [6-Me(3)-TPA, Tris(6-methyl-2-pyridylmethyl)amine] with O(2) in CH(2)Cl(2) at -80 degrees C gives rise to two new intermediates, 2 and 3, before the formation of previously characterized [Fe(2)(O)(O(2))(6-Me(3)-TPA)(2)](2+) (4) that allow the oxygenation reaction to be monitored one electron-transfer step at a time. Raman evidence assign...

Chromium Fischer carbene complexes with trans,trans-dienyl substituents on the carbene carbon will react with diiron nonacarbonyl to give 2-alkoxycyclohexa-2,4-dienone iron tricarbonyl complexes and/or 2-alkoxyphenols in excellent yields. In the presence of silica gel or base, the cyclohexadienone complex will suffer loss of the iron and aromatization to give 2-alkoxyphenols. The formation of 2...

The passage of water through certain bituminous coal mines results in a solution which is extremely acid in reaction because of its high content of ferrous sulfate, some aluminum sulfate, and lesser amounts of manganese sulfate. The ferrous iron is subsequently rapidly oxidized to the ferric state by an autotrophic bacterium. Autotrophic bacteria have also been implicated in the formation of th...

Backraund; Thiols are important elements for oxidation reactions and under oxidative stress. The aim of this study was to determine thiole levels, an antioxidative marker in CAD patients with stable acute coronary syndrome. Methods; 210 the included were diagnosed syndrome (ACS), 205 consisted angina pectoris (SAP). Thiol groups levels thiol/disulphide homeostasis measured by spectrophotometric...

Carbon disulfide (CS2) is a typical organic sulfur compound emitted from many industrial processes, such as petrochemical, smelting, et al. Chemical adsorption promising method for CS2 removal and Fe based adsorbents usually show excellent performance. Single-atom catalysts (SACs) always perform magical effects in various heterogeneous reactions. In this work, pyrolyzing coordinated polymer (PC...

Escherichia coli RIC (Repair of Iron Centers) is a diiron protein previously reported to be involved in the repair of iron-sulfur proteins damaged by oxidative or nitrosative stresses, and proposed to act as an iron donor. This possible role of RIC was now examined specifically by evaluating its ability to donate iron ions to apo-iron-sulfur proteins, determining the iron binding constants and ...

background : among the industrial activities that may cause odor nuisance problems, baking waste one is of the sources of bad odor, and therefore individuals complain from the industry. the aim of this study was to evaluation of pollutants released from poultry rendering plant and also performance of existing refiners in removing these pollutants.   methods : in this study, 66 air samples were ...