in this paper, the effect of cationic and anionic ion sizes on the charge storage capability of graphene nanosheets is investigated. the electrochemical properties of the produced electrode are studied using cyclic voltammetry (cv) and electrochemical impedance spectroscopy (eis) techniques in 3m nacl, naoh, and koh electrolytes. scanning electron microscopy (sem) is used to characterize the mi...

In this work, for the first time poly (benzoquinone) chromium (III) complex (PBQC) was synthesized with a one pot, one step, simple and fast method. This novel polymer was used for modification of graphite paste electrode for electrochemical determination of Mesalazine. Moreover, this novel modifier was characterized by Fourier transform infrared spectroscopy, Field emission scanning electron m...

This paper describes the development, electrochemical characterization and utilization of novel modified molybdenum (VI) complex-carbon nanotube paste electrode for the electrocatalytic determination of ascorbic acid (AA). The electrochemical profile of the proposed modified electrode was analyzed by cyclic voltammetry (CV) that showed a shift of the oxidation peak potential of AA about 235 mV ...

The present study aims at designing a promising Microbial Fuel Cell (MFC) to utilize wastewater in order to generate electricity. Two types of salt bridge have been used in MFC (KCl and NaCl). The maximum electricity generation with 1M KCl and NaCl has been 823 and 713 mV, respectively. Varied salt concentrations (0.5M, 1M, 2M, and 3M) of salt bridge in MFC have been analyzed with different fac...

2-Amino-N-benzthioazolyl benzamide (ABTB) was synthesized, characterized and used for thefabrication of a potentiometric sensor for Cu2+ metal ions. The electrode exhibits linear response to Cu(II) over a wide concentration range (4.79×10 -8 – 1.85×10 -1 M) with Nernstian slope of 30 ± 1.5 mVper decade. The electrode can be used in the pH range from 2 to 9. It has a fast response time of about1...

A PVC membrane electrode based on 1-[({[(butylsulfunyl)carbothioyl]disulfanyl} carbothioyl)sulfanyl]butane as a suitable ion carrier for determination of lanthanum(III) ion was prepared. This electrode revealedsuch a good selectivity toward La3+ ion over a wide variety of other metal ions. Some experimental parametersuch as membrane composition, nature, and amount of plasticizer, the amount of ...

The present study aims at designing a promising Microbial Fuel Cell (MFC) to utilize wastewater in order to generate electricity. Two types of salt bridge have been used in MFC (KCl and NaCl). The maximum electricity generation with 1M KCl and NaCl has been 823 and 713 mV, respectively. Varied salt concentrations (0.5M, 1M, 2M, and 3M) of salt bridge in MFC have been analyzed with different fac...

a physic-mathematical model has been developed that is suitable for biosensors incorporating membranes and bisubstrate enzymes. the set of equations regarding the transport of reactants across the membrane, the bisubstrate enzymatic reaction, back diffusion of reactants and reaction products, are written down and simultaneously solved and transient response of the electrode is determined as a f...

In this work we introduce a practical use of synthesized Schiff base metal complex in sensing application. A new perchlorate-selective electrode based on the complex N, N'-4-nitro-phenylmethanebis-(salicylaldiminato) copper (II) [CuL] as the membrane carrier was developed. The electrode exhibits a good  Nernstian slope of -55.0 ± 1.0 mV/decade and a linear range of  for perchlorate. The lim...

A rapid electrochemical technique was developed to determine 8-Hydroxyquinoline (8HQ). In the current study, the anionic surfactant Sodium lauryl sulfate (SLS) was immobilized on the multi-walled carbon nanotube (MWCNT) paste surface for the fabrication of electrode to detect 8HQ in phosphate buffer solution (PBS) of pH 7.0. The response of SLS modified carbon nanotube paste electrode (SLSMCNTP...