a new model based on a combination of the polymeric multigrain and multilayer models has been developed to predict the polymerization rate, particle growth, morphology, effective parameters on broadening of the molecular weight distribution, number and weight average of the molecular weight, isotacticity index and bulk density of polymer. mathematical correlations and the kinetics used in this ...

the cycloaddition reaction of diphenylnitrilimine on the 1,5-benzodiazepines has been studied. new molecules of triazolobenzodiazepines type have been isolated and characterized.

An ultra-high vacuum (UHV) setup for "real" and "inverse" model catalyst preparation, depth-resolved near-surface spectroscopic characterization, and quantification of catalytic activity and selectivity under technologically relevant conditions is described. Due to the all-quartz reactor attached directly to the UHV-chamber, transfer of the catalyst for in situ testing without intermediate cont...

Ultrasound assisted phase-transfer catalyzed preparation of ethyl 2-(4-nitrophenoxy)acetate from the corresponding p-nitrophenol and ethyl 2-bromoacetate using the mild solid base, anhydrous potassium carbonate, under very mild conditions is reported. The solid-liquid reactions were performed in a batch reactor equipped with reflux condenser, and ultrasonic irradiations were introduced using an...

in this paper a new method is introduced and investigated for removing the destabilizing effects of time-delay parameter in control loops. the concept of the method is taken from the knowledge concerning the dynamic behaviour of irrational transfer functions (ir-tf), which is discussed and investigated elswhere in frequency response domain and is explained briefly here. ir-tfs, which are well c...

The spillover phenomenon, which essentially involves transfer of H from a metal catalyst to a graphitic receptor, has been considered promising for efficient hydrogen storage. An open question about the spillover mechanism is how a H atom binds to graphene instead of forming the thermodynamically preferred H(2). Using ab initio calculations, we show that the catalyst saturation provides a way t...

Reactions proceeding through cationic intermediates that lack a Lewis or Brønsted basic site present a challenge for traditional asymmetric catalysis based on chiral metals or organocatalysts. We present an enantioselective ring opening of tetrasubstituted meso-aziridinium ions with alcohol nucleophiles proceeding through a chiral ion pair with a binaphthol-phosphate anion. The reaction is init...

the commercial profile of the amoco cd mgcl2 supported polypropylene catalyst is presented. the development, the unique method of preparation/production, with emphasis on particle morphology, and the parameters affecting particle size (ps), particle size distribution (psd), and particle shape are discussed in detail. the outstanding performance of the catalyst, tailoredmade for the amoco-chisso...

Water-splitting dye-sensitized photoelectrochemical cells (WSDSPECs) utilize high surface area TiO2 electrodes functionalized with light absorbing sensitizers and water oxidation catalysts. Because water splitting requires vectorial electron transfer from the catalyst to the sensitizer to the TiO2 surface, attaching both sensitizer and catalyst to TiO2 in the correct sequence and stabilizing th...