Abstract Surfactants tend to adsorb on the surface/interface mostly in a directional manner. The alkyl chain orientation and conformation order for molecular monolayers of sodium dodecylbenzenesulfonate (SDBS) at low concentrations are studied by using sum frequency generation vibrational spectroscopy (SFG-VS). arrangement surfactants adsorbed solid/liquid interface is further investigated. It ...

One of the great enemies of rubber compounds is heat. Heat will cause chemical and physical degradation of vulcanized rubber as well as a considerable loss in its strength. A major source of heat generation in a tire is due to internal friction resulting from the viscoelastic deformation of the tire as it rolls along the road. Another source of heat generation in a tire is due to its contact fr...

The molecular mechanism of slip at the interface between polymer melts and weakly attractive smooth surfaces is investigated using molecular dynamics simulations. In agreement with our previous studies on slip flow of shear-thinning fluids, it is shown that the slip length passes through a local minimum at low shear rates and then increases rapidly at higher shear rates. We found that at suffic...

Traditional analyses of slip at corners of contacts, based on linear elasticity and a Coulomb friction law, are very sensitive to the details of local geometries, owing to the effects of elastic singularities. Following the use of cohesive-zone models to address such issues in mode-II fracture, we present analyses of slip and wear at corners of contacts when a finite interfacial shear strength ...