Chalcogen-nitrogen chemistry deals with systems in which sulfur, selenium, or tellurium is linked to a nitrogen nucleus. This chemical motif key component of different functional structures, ranging from inorganic materials and polymers, rationally designed catalysts, bioinspired molecules enzymes. The formation selenium–nitrogen bond, typically occurring upon condensation an amine the unstable...

Selenium is an essential trace element that occurs in nature, in both inorganic and organic forms. This element participates in numerous biochemical processes, including antioxidant potential, but the mechanism of its anti-cancer action is still not well known. It should be noted that the anti-cancer properties of selenium depends on its chemical form, therapeutic doses, and the tumor type. Hig...

Aflatoxin B1 (AFB1), among other aflatoxins of the aflatoxin family, is the most carcinogenic and hazardous mycotoxin to animals and human beings with very high potency leading to aflatoxicosis. Selenium is an essential trace mineral possessing powerful antioxidant functions. Selenium is widely reported as an effective antioxidant against aflatoxicosis. By preventing oxidative liver damage, sup...

Excess consumption of selenium (Se) accumulator plants can result in selenium intoxication. The objective of the study reported here was to compare the acute toxicosis caused by organic selenium (selenomethionine) found in plants with that caused by the supplemental, inorganic form of selenium (sodium selenite). Lambs were orally administered a single dose of selenium as either sodium selenite ...

Selenosugars are a group of sugar derivatives great structural diversity (e.g., molar masses, selenium oxidation state, and binding), obtained as result biosynthesis, chemical modification natural compounds, or synthesis. Seleno-monosaccharides disaccharides known to be non-toxic products the metabolism compounds in mammals. In case selenium-containing polysaccharides origin, their formation is...

A variety of extraction procedures were evaluated for the extraction of arsenic and other analytes from lobster tissue samples using inductively coupled plasma mass spectrometry (ICP-MS) detection. Soxhlet, room temperature mixing, sonication, microwave assisted, supercritical carbon dioxide and subcritical water extractions were evaluated for a variety of solvent systems and optimum conditions...

Arsenic is the most toxic metalloid present in the natural environment in both organic and inorganic arsenic forms. Inorganic arsenic is often more hazardous than the organic form. Arsenite and arsenate compounds are the major inorganic forms which are toxic causing severe human health dysfunction including cancer. Excretion of arsenic from the system is found elusive. Therefore, it is of inter...

Combustion of fossil fuels has been the backbone of the power generation, manufacturing and transportation industries in the twentieth century. Although the mix of fuels has changed, at the close of the century we find that combustion systems have not changed overmuch. Operational caused by inorganic elements in fossil fuels (corrosion, slagging, and fouling) continue to present problems in com...

Selenium is an essential nutrient for animals, microorganisms and some other eukaryotes. Although selenium has not been demonstrated to be essential in vascular plants, the ability of some plants to accumulate and transform selenium into bioactive compounds has important implications for human nutrition and health, and for the environment. Selenium-accumulating plants provide unique tools to he...

For a long period, Selenium was considered mainly a toxic element and has been the object of disputes for its controversial balance between beneficial and toxic effects. Nowadays, many evidences demonstrated its role as essential microelement in mammalian diet, having an essential role in redox homeostasis of all the living systems. Around 25 proteins were discovered to contain a selenocysteine...