trifluoromethylated organic compounds, especially chiral quaternary alcohols bearing trifluoromethyl group are of important intermediates in drugs, agrochemicals and etc.an efficient epoxidation of β-cf3-β,β-disubstituted unsaturated ketones (6) has been developed with environmental benign hydrogen peroxide as the oxidant and f5-substituted chiral quaternary ammonium salt (1g or 5) derived from...

gem-dihydroperoxides as nearly stable peroxidic derivatives of aldehydes and ketones are known important intermediates in synthesis of anti-malaria drugs. also, because containing high concentration of peroxidic oxygen, recently, some of these compounds have been used as solid, efficient and powerful oxidants in many oxidation organic reactions. generally, these compounds are synthesized via pe...

In the presence of hydrogen peroxide and either potassium iodide, sodium chloride, or potassium bromide, purified human myeloperoxidase was rapidly lethal to several species of Candida. Its candidacidal activity was inhibited by cyanide, fluoride, and azide, and by heat inactivation of the enzyme. A hydrogen peroxidegenerating system consisting of d-amino acid oxidase, flavine-adenine dinucleot...

When hydrogen peroxide is mixed with caustic soda, an auto-accelerating reaction can lead to gen­ eration of significant amounts of heat and oxygen. On the basis of experiments using typical pulp mill process con­ centration and temperatures, a relatively simple kinetic model has been developed. Evaluation of these model results reveals that hydrogen peroxide-caustic soda systems are extremely ...

In this and following papers, the properties of two new catalytically active enzyme-substrate compounds of catalase are given. Paper I gives spectroscopic data, Paper II and III, data on kinetics and activity, and, in Paper IV, the reactions of these enzyme-substrate compounds with hydrogen peroxide are discussed. The red catalase ethyl hydrogen peroxide compound studied by Stern (1) is charact...

There has been recent concern about the inadvertent exposure of dentin with patent tubules as well as gingiva to bleaching systems containing 10-15% carbamide peroxide or 2-10% hydrogen peroxide for more than a few minutes. The aims of the present study were: (1) to determine the cytotoxicity of dilutions of hydrogen peroxide in cell culture; (2) to measure hydrogen peroxide diffusion from blea...

Rapid detection of the hydrogen peroxide precursor of peroxide explosives is required in numerous security screening applications. We describe a highly sensitive and selective amperometric detection of hydrogen peroxide vapor at an agarose-coated Prussian-blue (PB) modified thick-film carbon transducer. The sensor responds rapidly and reversibly to dynamic changes in the level of the peroxide v...

In this and following papers, the properties of two new catalytically active enzyme-substrate compounds of catalase are given. Paper I gives spectroscopic data, Paper II and III, data on kinetics and activity, and, in Paper IV, the reactions of these enzyme-substrate compounds with hydrogen peroxide are discussed. The red catalase ethyl hydrogen peroxide compound studied by Stern (1) is charact...

The solution of hydrogen peroxide is a critical ingredient of the Weber luminol application for blood detection at the crime scene. An ideal alternative to the unstable hydrogen peroxide is a solid compound which is easy to transport, stable and quick to solve in water at the crime scene. Carbamide peroxide (urea peroxide) is one of these solid hydrogen peroxide carriers which is easy to obtain...