Adsorption of hydrogen on graphdiyne (GDY) and boron-graphdiyne (BGDY) doped with palladium clusters has been investigated by performing density functional calculations. Pd6 fits well the large holes those porous layers, preserving its octahedral structure in GDY changing it to a capped trigonal bipyramid BGDY. Pd6GDY adsorbs up five H2 molecules sizable adsorption energies, two dissociated thr...

In the title compound, C(35)H(30)N(4)P(2), the diphenyl-phosphanyl and diphen-yl(2-pyridyl-imino)-λ(5)-phosphanyl groups are attached to the central methyl C atom with a P-C-N angle of 114.09 (16)°. The mol-ecules stack along the b axis and inter-connect through C-H(pyrid-yl)⋯N(pyrid-yl) inter-actions, forming an infinite chain structure. The parallel chains are further inter-connected via C-H(...

The complete mol-ecule of the title compound, C(12)H(10)ClO(2)PS, is generated by crystallographic mirror symmetry, with the P, S and Cl atoms lying on the mirror plane. The resulting PO(2)SCl tetra-hedron is significantly distorted [O-P-O = 96.79 (9)°]. The crystal packing exhibits no directional inter-actions.