Hydrogen peroxide was encapsulated into a silica xerogel matrix by the sol-gel technique. The composite was tested as an oxidizing agent both under conventional and microwave conditions in a few model reactions: Noyori's method of octanal and 2-octanol oxidation and cycloctene epoxidation in a 1,1,1-trifluoroethanol/Na2WO4 system. The results were compared with yields obtained for reactions wit...

background: poly chlorinated biphenyls (pcbs) are a class of chlorinated organic chemicals that do not easily degrade in the environment. this study was conducted to determine the effect of microwave rays, hydrogen peroxide, dioxide titanium and ethanol solvent on the degradation of pcbs. methods: a 900w domestic mw oven with a fixed frequency of 2450 mhz was used to provide mw irradiation. ray...

The simultaneous application of ultrasonic irradiation with ozonation was demonstrated to be effective for the oxidation of oxalic acid (H2C2O4/HC2O4/C2O4), a particularly recalcitrant pollutant, to CO2 and H2O. Degradation rates obtained using sonolytic ozonation were found to be more than 16-times faster than predicted by the linear addition of the independent systems. Model calculations and ...

Vascular endothelial cells (ECs) are constantly subjected to pressure-induced strain. We have previously demonstrated that strain can induce intercellular adhesion molecule-1 (ICAM-1) expression in ECs. The molecular mechanisms of gene induction by strain, however, remain unclear. Recent evidence suggests that intracellular reactive oxygen species (ROS) may act as second messengers. The potenti...

Iron (hydr)oxides are ubiquitous earth materials that have high adsorption capacities for toxic elements and degradation ability towards organic contaminants. Many studies have investigated the reactivity of synthetic magnetite, while little is known about natural magnetite. Here, we first report the reactivity of natural magnetites with a variety of elemental impurities for catalyzing the deco...

The chemical decomposition of p-hydroxyphenylacetic acid, a priority phenolic pollutant present in wastewaters from some agro-industrial plants, is studied by means of a single photochemical process produced by a polychromatic UV radiation and by hydroxyl radicals generated by the combination of UV radiation plus hydrogen peroxide and by the Fenton's reagent (hydrogen peroxide plus ferrous salt...

Recent progress in the development of phenylboronic acid (PBA)-functionalized layer-by-layer (LbL) assemblies and their biomedical applications was reviewed. Stimuli-sensitive LbL films and microcapsules that exhibit permeability changes or decompose in response to sugars and hydrogen peroxide (H2O2) have been developed using PBA-bearing polymers. The responses of PBA-modified LbL assemblies ar...

Both catalase and peroxiredoxin show high activities of H2O2 decomposition coexist in the same organism; however, their division labor defense against is unclear. We focused on major (PrxA) (CatB) Aspergillus nidulans at different growth stages to discriminate antioxidant roles. The dormant conidia lacking PrxA showed sensitivity concentrations (>100 mM), revealing that one important antioxi...