The dielectric response of pentagonal defects in multilayer graphene nano-cones has been studied by electron energy loss spectroscopy and ab initio simulations. At the cone apex, a strong modification of the dielectric response is observed below the energy of the π plasmon resonance. This is attributed to π → π* interband transitions induced by topology-specific resonant π bonding states as wel...

For the first time a novel oxygen reduction catalyst with a 3D platinized graphene/nano-ceramic sandwiched architecture is successfully prepared by an unusual method. Herein the specific gravity of graphene nanosheets (GNS) is tailored by platinizing graphene in advance to shorten the difference in the specific gravity between carbon and SiC materials, and then nano-SiC is well intercalated int...

The nano-Bi2WO6/reduced graphene oxide composite obtained by a simple hydrothermal reaction demonstrates a larger specific capacitance of 922 F/g at a charge and discharge currents of 3 A/g with longer cycle life. The As comparison, pristine Bi2WO6 nanoparticles have poor specific capacitance of 574 F/g at a charge and discharge currents of 2 A/g with weak cycle life. Though analyzing the Cycli...

We propose an unprecedented transmit-array configuration which can mold the incident beam by modulating phase and amplitude wavefronts. The transmit-array is composed of patterned graphene metasurfaces as shunt admittance sheets. Thanks to the exceptional features of graphene such as tunability, thinness, low loss, and high confinement of graphene plasmons, the proposed subwavelength structure ...

C arbon, a vital element in our daily lives, is still fascinating us at the nanoscale. In PNAS, Geng et al. (1) manage to synthesize ordered arrays of atom-thick hexagonal microplatelets consisting of sp hybridized carbon. Since the discovery of C60 (Buckminsterfullerene; an icosahedral carbon cage molecules with diameter of approximately 0.7 nm) (2), carbon nanoscience emerged, and it was witn...

Dispersion of nanomaterials in polymeric matrices plays an important role in determining the final properties of the composites. Dispersion in nano scale, and especially in single layers, provides best opportunity for bonding. In this study, we propose that by proper functionalization and mixing strategy of graphene its dispersion, and bonding to the polymeric matrix can be improved. We then ap...

Graphene, a two dimensional structure of carbon atoms, has been widely used as a material for gas sensing applications because of its large surface area, excellent conductivity, and ease of functionalization. This article reviews the most recent advances in graphene hybrid materials developed for gas sensing applications. In this review, synthetic approaches to fabricate graphene sensors, the n...

Recent years have witnessed considerable interest devoted to the electronic properties of graphene [1-3]. Graphene, a one-atom-thick sheet of carbon atoms arranged in a honeycomb crystal, exhibits unique properties like high thermal conductivity, high electron mobility and optical transparency, and has the potential for use in nano-electronic and optoelectronic devices. With the size of these d...

A new driving mechanism for direction-controlled motion of nano-scale objects is proposed, based on a model of stretching a graphene strip linked to a rigid base with linear springs of identical stiffness. We find that the potential energy difference induced by the strain gradient field in the graphene strip substrate can generate sufficient force to overcome the static and kinetic friction for...

Address correspondence to [email protected] ABSTRACT Graphene has many unique properties that make it an ideal material for fundamental studies as well as for potential applications. Here we review recent results on the Raman spectroscopy and imaging of graphene. We show that Raman spectroscopy and imaging can be used as a quick and unambiguous method to determine the number of graphene layers...