the electrochemical behaviour of lead electrode in hydrochloride solution containing variousoxo-anions at different concentrations was studied by using of cyclic voltammetry (cv) method.results obtained show that the addition of these inorganic compounds decreases the anodic andcathodic currents peaks according to the following order: h2po4- > hpo42-> so42-. it’s revealedalso that the cathodic ...

background: there are great resources of natural zeolite in iran. zeolite, an inorganic ion-exchanger, may be used as a suitable technical-economical solution for water treatment in many regions of iran. in this study, the characterization of natural zeolite natrolite and the feasibility of removing hardness, cations, and anions were investigated. methods: first, zeolite composition and type we...

Partition coefficients from water to organic solvents for phenoxide anions have been obtained using a method based on the variation of pK(a) of phenols with solvent. From these partition coefficients, the Abraham descriptors for phenoxide anions, on the same scale as descriptors for neutral molecules, have been obtained. Equations have been constructed for the prediction of descriptors, and val...

A new azo-azomethine chemosensor containing active phenolic sites, H2L, has been designed and synthesized for rapid detection of inorganic fluoride over the other anions, such as Clˉ, Brˉ, Iˉ, AcOˉ, H2PO4ˉ, NO3ˉ, N3ˉ in DMSO/water (90/10) media. The 1H NMR titration revealed that the colorimetric response was considered to be the direct consequence of hydrogen-bond formation between phenolic gr...

The chemistry of nine-atom deltahedral Zintl anions of Group 14 has advanced greatly in recent years. Redox reactions of these clusters have led to dimers, trimers, tetramers, and infinite chains of germanium clusters such as [Ge9-Ge9] 6 , [Ge9=Ge9=Ge9] 6 , [Ge9=Ge9=Ge9=Ge9] 8 , 1[-(Ge9) 2 -], and 1[-(HgGe9) 2 -]. Similar redox reactions combined with nucleophilic addition of various anions hav...

Contractions of skeletal muscles produce increases in concentrations of superoxide anions and activity of hydroxyl radicals in the extracellular space. The sources of these reactive oxygen species are not clear. We tested the hypothesis that, after a demanding isometric contraction protocol, the major source of superoxide and hydroxyl radical activity in the extracellular space of muscles is mi...