Abstract Gasification and combustion are two common methods for Zhundong (ZD) coal utilization. In the present study, it was intended to investigate thermal transformation of Na in ZD at Lurgi fixed bed gasifier (Lurgi) circulating fluidized boiler (CFBB). To this end, raw samples before gasification gasified slags were gathered from Lurgi, combustion, burned slag, fly ash collected CFBB. The o...