The effect of three organic aromatic salts - Phenyltrimethylammonium (PhTMAB), benzyltrimethylammonium (BzTMAB) and benzyltrimethylammonium (BzTEAB) bromides - on the micellization of sodium dodecylsulfate has been investigated by conductometric method. The critical micelle concentration (CMC) values were found to decrease with increase in the concentration of the aromatic ammonium salts. Therm...

Oxy-fuel combustion is recognized one of the most promising available technologies that zero emission accomplishment may be in the offing. With coal burned under the pressure of 6MPa and oxygenenriched conditions, the high temperature and high pressure gaseous combustion product is composed of 95% CO2 and water-vapor, with the rest of O2, N2 and so on. However, once lauded as classic approach o...

We describe flame propagation between two opposed reactive streams which may differ in their composition and temperature. A two-dimensional counterflow configuration and an irreversible Arrhenius reaction are adopted, along with the constant density approximation. Attention is focused on the influence of two nondimensional parameters. The first one, denoted by g, represents the difference in th...

Hydrophobic association is often recognized as being driven by favorable entropic contributions. Here, using explicit solvent molecular dynamics simulations we investigate binding in a model hydrophobic receptor-ligand system which appears, instead, to be driven by enthalpy and opposed by entropy. We use the temperature dependence of the potential of mean force to analyze the thermodynamic cont...

thermodynamic study on the interaction of β-cd with poly ethylene oxide and poly acrylic acid was performed by isothermal titration calorimetry at 298k. when β-cd is added to the interpolymer complex, competition is created between host-guest and hydrogen bond. enthalpy of interaction between the β-cd and interpolymer complex was calculated using the extended solvation theory. p=1 shows that wi...